Combined influence of carrier mobility and dielectric constant on the performance of organic bulk heterojunction solar cells

It has been shown that there is an optimum charge carrier mobility that leads to a peak in the efficiency for organic bulk heterojunction solar cells with mobility-dependent recombination rate. Hence, improving the mobility is considered as one of the ways to increase the efficiency. In this study,...

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Bibliographic Details
Published in:AIP advances 2014-05, Vol.4 (5), p.057133-057133-11
Main Authors: Inche Ibrahim, M. L., Ahmad, Zubair, Sulaiman, Khaulah, Muniandy, S. V.
Format: Article
Language:English
Subjects:
Carrier mobility
Current carriers
Efficiency
Heterojunctions
Permittivity
Photovoltaic cells
Solar cells
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Summary:It has been shown that there is an optimum charge carrier mobility that leads to a peak in the efficiency for organic bulk heterojunction solar cells with mobility-dependent recombination rate. Hence, improving the mobility is considered as one of the ways to increase the efficiency. In this study, we investigate the combined influence of charge carrier mobility and dielectric constant on the performance of organic bulk heterojunction solar cells by performing drift-diffusion calculations. We find that a higher dielectric constant leads to a higher peak efficiency together with a lower optimum mobility. We also find that if the dielectric constant of the active material can be increased significantly (to around 8 or higher), it is then possible that the mobility of the active material need not to be improved in order to achieve the maximum efficiency. This study demonstrates the importance of knowing the interplay between the mobility and the dielectric constant with regard to the efficiency.
ISSN:2158-3226
2158-3226
DOI:10.1063/1.4881080