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Structure and Crystallization of Glasses in the MnNbOF5–BaF2–InF3 System

Glasses of the MnNbOF 5 –BaF 2 –InF 3 system were prepared. The structure, thermal behavior, and crystallization of these glasses were studied by IR and Raman spectroscopy, differential scanning calorimetry (DSC), X-ray powder diffraction, and microscopy. The N b O 2 F 4 3 − and I n F 6 3 − ions for...

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Published in:Russian journal of inorganic chemistry 2018-11, Vol.63 (11), p.1389-1394
Main Authors: Ignat’eva, L. N., Savchenko, N. N., Marchenko, Yu. V., Zverev, G. A., Buznik, V. M.
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description Glasses of the MnNbOF 5 –BaF 2 –InF 3 system were prepared. The structure, thermal behavior, and crystallization of these glasses were studied by IR and Raman spectroscopy, differential scanning calorimetry (DSC), X-ray powder diffraction, and microscopy. The N b O 2 F 4 3 − and I n F 6 3 − ions form a mixed glass network. Glass crystallization occurs in one or two steps depending on the component ratio. The major crystal phases are Ba 3 In 2 F 12 and BaNbOF 5 . The obtainability of transparent crystal-glass samples in MnNbOF 5 –BaF 2 –InF 3 glasses via heat treatment is shown.
doi_str_mv 10.1134/S0036023618110062
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subjects Barium fluorides
Chemistry
Chemistry and Materials Science
Crystallization
Glass
Heat treatment
Infrared spectroscopy
Inorganic Chemistry
Raman spectroscopy
Synthesis and Properties of Inorganic Compounds
Thermodynamic properties
X ray powder diffraction
X ray spectra
title Structure and Crystallization of Glasses in the MnNbOF5–BaF2–InF3 System
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