Non-symmetric chiral nematic liquid crystal dimers containing trifluoromethyl and 1,2-propanediol

• Published in: Liquid crystals 2018-09, Vol.45 (12), p.1734-1745
• Main Authors: Dong, Liang, Xu, Zhi-xin, Tao, He-zhong, Chen, Xin-shi, Hu, Jian-she, Yao, Dan-shu, Tian, Mei
• Format: Article
• Language: English
• Subjects: 1,2-propanediol; Calorimetry; Chemical bonds; chiral nematic phase; Cholesteric liquid crystals; Differential scanning calorimetry; Dimers; fluorinated liquid crystal; Fluorination; Microscopy; Nematic crystals; NMR; Non-symmetric liquid crystal dimer; Nuclear magnetic resonance; Optical activity; Optical microscopy; Organic chemistry; Rigidity; Thermal properties; Thermodynamic properties; Thermogravimetric analysis; X-ray diffraction
• ISSN: 0267-8292; 1366-5855
• DOI: 10.1080/02678292.2018.1469171

A series of non-symmetric liquid crystal (LC) dimers with the same chiral core 1,2-propanediol (PD) have been synthesised, termed as ABBA-PD-TFBA, PBBA-PD-TFBA, ABA-PD-TFBA, PBA-PD-TFBA and AA-PD-TFBA, respectively, in which one of the two mesogenic groups, the fluorinated mesogenic unit, was kept fix and the other arm was different. The intermediate compounds and LC dimers were characterised by FTIR, 1 H NMR, differential scanning calorimetry, thermogravimetric analysis, polarised optical microscopy and X-ray diffractometer (XRD). The results of the measurements indicated that ABBA-PD-TFBA, PBBA-PD-TFBA and ABA-PD-TFBA displayed optical activity and enantiotropic chiral nematic phase, and PBA-PD-TFBA was an enantiotropic nematic LC while AA-PD-TFBA was a monotropic LC, displaying both nematic phase and smectic A phase on cooling. The results indicated that PD was able to induce the chiral nematic phase, nevertheless, the rigidity of the mesogenic arm, the flexibility of the terminal group and even the type of the terminal chemical bond played an important effect on the thermal properties of the dimers, and even on the formation of the chiral nematic phase. It is also worth noting that C=C at the terminal helped to stabilise the LC phase.