Syntheses and Physical-Chemical Properties of Phenylvinylidene Complexes with MnPt Core, Containing Diphenylphosphine Ligand at the Platinum Atom

A synthetic approach to the new heterobinuclear p-phenylvinylidene complexes Cp(CO)2MnPt(p-C=CHPh)(PPh2H)(L) [L = PPh3 (1), P(OPri3 (2)], containing diphenylphosphine ligand at the platinum atom, was developed. The compounds were studied by IR- and NMR-spectroscopy. Their molecular structures were p...

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Bibliographic Details
Published in:Journal of Siberian Federal University. Chemistry 2018-07, Vol.11 (3), p.390-400
Main Authors: Chudin, Oleg S, Verpekin, Victor V, Kondrasenko, Alexander A, Pavlenko, Nina I, Rubaylo, Anatoly I
Format: Article
Language:Russian
Subjects:
Chemical properties
Chemistry
Crystal structure
Infrared spectroscopy
Ligands
NMR
Nuclear magnetic resonance
Organic chemistry
Platinum
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Summary:A synthetic approach to the new heterobinuclear p-phenylvinylidene complexes Cp(CO)2MnPt(p-C=CHPh)(PPh2H)(L) [L = PPh3 (1), P(OPri3 (2)], containing diphenylphosphine ligand at the platinum atom, was developed. The compounds were studied by IR- and NMR-spectroscopy. Their molecular structures were proposed based on IR, NMR spectroscopic data.
ISSN:1998-2836
2313-6049
DOI:10.17516/1998-2836-0085