Some New Reactions and Properties of Xanthane Hydride (5-Amino-1,2,4-dithiazole-3-thione)

Aminomethylation of xanthane hydride (5-amino-1,2,4-dithiazole-3-thione) with the RNH 2 –HCHO system has resulted in the formation of the derivatives of new heterocyclic system (3,7-dihydro-5 H -[1,2,4]-dithiazolo[4,3- a ][1,3,5]triazine) in low yields. The reaction of xanthane hydride with dicyandi...

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Bibliographic Details
Published in:Russian journal of general chemistry 2018-10, Vol.88 (10), p.2050-2057
Main Authors: Dotsenko, V. V., Evmeshchenko, T. Yu, Aksenov, N. A., Aksenova, I. V., Krapivin, G. D., Sharapa, D. I., Chausov, F. F., Strelkov, V. D., Dyadyuchenko, L. V.
Format: Article
Language:English
Subjects:
Aqueous solutions
Carbon steel
Carbon steels
Chemical properties
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Corrosion
Derivatives
Hydrides
Nuclear magnetic resonance spectroscopy
Steel
Sulfur compounds
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Summary:Aminomethylation of xanthane hydride (5-amino-1,2,4-dithiazole-3-thione) with the RNH 2 –HCHO system has resulted in the formation of the derivatives of new heterocyclic system (3,7-dihydro-5 H -[1,2,4]-dithiazolo[4,3- a ][1,3,5]triazine) in low yields. The reaction of xanthane hydride with dicyandiamide has led to thioammeline [4,6-diamino-1,3,5-triazine-2(5 Н )-thione]. Some practically important properties of xanthane hydride and its derivatives have been investigated. Xanthane hydride has efficiently exhibited carbon steel corrosion in neutral aqueous media. The prepared compounds have not exhibited growth-regulating or antidote activity to herbicide 2,4-D.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363218100043