Cerium(IV)‐Promoted Phosphinoylation‐Nitratation of Alkenes

A Cerium(IV)‐promoted phosphinoylation‐nitratation of alkenes is established under mild conditions. In this process, Ceric ammonium nitrate (CAN) acts as a cheap phosphorus‐radical initiator, as well as a nitrate donor. Various β‐nitrooxyphosphonates are delivered in high yield in a one‐pot manner....

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Bibliographic Details
Published in:Advanced synthesis & catalysis 2018-12, Vol.360 (23), p.4470-4474
Main Authors: Yang, Bin, Hou, Shu‐Min, Ding, Shi‐Yu, Zhao, Xiao‐Nan, Gao, Yuan, Wang, Xue, Yang, Shang‐Dong
Format: Article
Language:English
Subjects:
Alkenes
Ammonium nitrate
Cerium ammonium nitrate
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Summary:A Cerium(IV)‐promoted phosphinoylation‐nitratation of alkenes is established under mild conditions. In this process, Ceric ammonium nitrate (CAN) acts as a cheap phosphorus‐radical initiator, as well as a nitrate donor. Various β‐nitrooxyphosphonates are delivered in high yield in a one‐pot manner. magnified image
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.201800985