Effects of the molecular weight and CC functionality of poly 1‐hexene on the properties of poly 1‐hexene‐based high impact polystyrene

ABSTRACT Here we are aimed to unravel the effects of CC functionality and molecular weight of the rubber on the final properties of poly1‐hexene‐based high impact polystyrenes (HIPS). In this regard, various HIPS samples were synthesized by free radical polymerization of styrene in the presence of...

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Bibliographic Details
Published in:Journal of applied polymer science 2019-03, Vol.136 (10), p.n/a
Main Authors: Hanifpour, Ahad, Bahri‐Laleh, Naeimeh
Format: Article
Language:English
Subjects:
Chemical synthesis
Free radical polymerization
Free radicals
Hexadiene
HIPS
Impact modifiers
Low molecular weights
Materials science
Molecular weight
poly1‐hexene
Polymers
polyolefins
Polystyrene resins
radical polymerization
Rubber
Thermodynamic properties
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Summary:ABSTRACT Here we are aimed to unravel the effects of CC functionality and molecular weight of the rubber on the final properties of poly1‐hexene‐based high impact polystyrenes (HIPS). In this regard, various HIPS samples were synthesized by free radical polymerization of styrene in the presence of different weight fractions of various poly1‐hexene‐based impact modifiers including: (i) high molecular weight poly1‐hexene (PHex), (ii) low molecular weight poly1‐hexene (Olig), and (iii) 1‐hexene/1,5‐hexadiene copolymer (Copolym). Results showed that by increasing CC functionality from PHex to Oligm and Copoly, the degree of grafting increases which has its influence on the mechanical, thermal and morphological perspectives of the synthesized HIPSs. Besides CC unsaturation degree, the effect of rubber molecular weight on the final HIPS properties was studied as well. According to the results, molecular weight has significant effect on the final HIPS performance, too. Finally, our obtained results suggest new HIPS/Copolym sample as the one with the highest mechanical and thermal properties which is comparable well with commercial HIPS/polybutadiene grades. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47169.
ISSN:0021-8995
1097-4628
DOI:10.1002/app.47169