Esterification of Tertiary Amides by Alcohols Through C−N Bond Cleavage over CeO2

The front cover artwork for our 10th Anniversary Issue is provided by the research groups of Ken‐ichi Shimizu at Hokkaido University and Kazunari Yoshizawa at Kyushu University (Japan). The image shows a C−N bond cleavage reaction catalyzed by CeO2. See the Full Paper itself at https://doi.org/10.10...

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Bibliographic Details
Published in:ChemCatChem 2019-01, Vol.11 (1), p.15-15
Main Authors: Toyao, Takashi, Nurnobi Rashed, Md, Morita, Yoshitsugu, Kamachi, Takashi, Hakim Siddiki, S. M. A., Ali, Md. A., Touchy, Abeda S., Kon, Kenichi, Maeno, Zen, Yoshizawa, Kazunari, Shimizu, Ken‐ichi
Format: Article
Language:English
Subjects:
Alcohols
Amides
Cerium oxides
Cleavage
Esterification
Online Access:Get full text
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Summary:The front cover artwork for our 10th Anniversary Issue is provided by the research groups of Ken‐ichi Shimizu at Hokkaido University and Kazunari Yoshizawa at Kyushu University (Japan). The image shows a C−N bond cleavage reaction catalyzed by CeO2. See the Full Paper itself at https://doi.org/10.1002/cctc.201801098. “Experimental and computational investigations indicate that cooperative effects of acid‐base functions of CeO2 are key for the efficient promotion of alcoholysis reactions of tertiary amides through C−N bond cleavage to form esters.” This and more about the story behind the research featured on the front cover can be found in this issue's Cover Profile. Read the full text of the corresponding research at https://doi.org/10.1002/cctc.201801098.
ISSN:1867-3880
1867-3899
DOI:10.1002/cctc.201801865