A novel electrochemical epinine sensor using amplified CuO nanoparticles and a n -hexyl-3-methylimidazolium hexafluorophosphate electrode

This study suggests a carbon paste electrode modified with CuO nanoparticles and n -hexyl-3-methylimidazolium hexafluorophosphate (CPE/CuO-NPs/HMIPF 6 ) as a powerful tool for the analysis of epinine for the first time. It has been confirmed that CPE/CuO-NPs/HMIPF 6 can improve the sensitivity of ep...

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Published in:New journal of chemistry 2019, Vol.43 (5), p.2362-2367
Main Authors: Karimi-Maleh, Hassan, Sheikhshoaie, Mahdieh, Sheikhshoaie, Iran, Ranjbar, Mohammad, Alizadeh, Javad, Maxakato, Nobanathi Wendy, Abbaspourrad, Alireza
Format: Article
Language:English
Subjects:
Electrodes
Nanoparticles
Oxidation
Square waves
Urine
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cited_by cdi_FETCH-LOGICAL-c259t-a716d27bd48437343a02cfb5cbae7ba47b240699f43d2c9b9b9b49f8ba939ee43
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container_title New journal of chemistry
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creator Karimi-Maleh, Hassan
Sheikhshoaie, Mahdieh
Sheikhshoaie, Iran
Ranjbar, Mohammad
Alizadeh, Javad
Maxakato, Nobanathi Wendy
Abbaspourrad, Alireza
description This study suggests a carbon paste electrode modified with CuO nanoparticles and n -hexyl-3-methylimidazolium hexafluorophosphate (CPE/CuO-NPs/HMIPF 6 ) as a powerful tool for the analysis of epinine for the first time. It has been confirmed that CPE/CuO-NPs/HMIPF 6 can improve the sensitivity of epinine electro-oxidation and reduce the overvoltage of this drug compared to an unmodified electrode. The CuO nanoparticles are characterized by XRD and TEM methods. The CPE/CuO-NPs/HMIPF 6 exhibited a detection limit of 0.2 μM and a dynamic range of 0.7–900 μM for analysis of epinine by the square wave voltammetric method. Epinine determination was performed successfully by CPE/CuO-NPs/HMIPF 6 in serum and urine samples.
doi_str_mv 10.1039/C8NJ05581E
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source Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list)
subjects Electrodes
Nanoparticles
Oxidation
Square waves
Urine
title A novel electrochemical epinine sensor using amplified CuO nanoparticles and a n -hexyl-3-methylimidazolium hexafluorophosphate electrode
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