Preparation of Co3O4/nitrogen-doped carbon composite by in situ solvothermal with ionic liquid and its electrochemical performance as lithium-ion battery anode

• Published in: Ionics 2019-02, Vol.25 (2), p.475-482
• Main Authors: Xiao, Mingjun, Meng, Yanshuang, Duan, Chaoyu, Hu, Qianru, Li, Ruinian, Zhu, Fuliang, Zhang, Yue
• Format: Article
• Language: English
• Subjects: Anodes; Carbon; Chemistry; Chemistry and Materials Science; Cobalt oxides; Condensed Matter Physics; Electrochemical analysis; Electrochemistry; Electrode materials; Energy Storage; Ionic liquids; Ions; Lithium; Lithium-ion batteries; Nitrogen; Optical and Electronic Materials; Original Paper; Rechargeable batteries; Renewable and Green Energy; Synergistic effect; Transmission electron microscopy; X-ray diffraction
• ISSN: 0947-7047; 1862-0760
• DOI: 10.1007/s11581-018-2831-9

In this work, the Co 3 O 4 /nitrogen-doped carbon (Co 3 O 4 /NDC) composite was prepared by in situ solvothermal method using ionic liquid as carbon and nitrogen sources. The Co 3 O 4 /NDC composite was characterized by X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), and electrochemical testing. The HRTEM results show that there is a thin layer of amorphous carbon film on the surface of Co 3 O 4 particles, which can improve the conductivity of Co 3 O 4 and inhibit the fragmentation of material caused by volume expansion. When the Co 3 O 4 /NDC composite is used as the anode material of lithium-ion batteries, the reversible capacity is 1056 mAh g −1 after 50 cycles at 0.1 C. The superior electrochemical performance can be attributed to the synergistic effect of amorphous carbon film, nitrogen doping, and Co 3 O 4 particles.