Comparison of Resolving Power and Separation Time in Thermal Field-Flow Fractionation, Hydrodynamic Chromatography, and Size-Exclusion Chromatography

A general framework for a theoretical comparison of the capabilities of various methods for the separation of polymers according to molecular mass is presented. The capabilities of the different methods under optimized working conditions are compared in terms of their ability to produce a desired re...

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Bibliographic Details
Published in:Analytical chemistry (Washington) 1994-04, Vol.66 (7), p.1147-1160
Main Authors: Stegeman, Gerrit, van Asten, Arian C, Kraak, Johan C, Poppe, Hans, Tijssen, Robert
Format: Article
Language:English
Subjects:
Analytical chemistry
Chemistry
Chromatographic methods and physical methods associated with chromatography
Exact sciences and technology
Other chromatographic methods
Polymers
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Description
Summary:A general framework for a theoretical comparison of the capabilities of various methods for the separation of polymers according to molecular mass is presented. The capabilities of the different methods under optimized working conditions are compared in terms of their ability to produce a desired resolution between two polymer fractions in the shortest possible time.
ISSN:0003-2700
1520-6882
DOI:10.1021/ac00079a033