Instrumental, theoretical and experimental aspects of determining thermodynamic and kinetic parameters from steady-state and non-steady-state cyclic voltammetry at microelectrodes in high-resistance solvents

Instrumental, experimental and theoretical approaches required to quantify the thermodynamic and kinetic aspects of the square reaction scheme relating the facplus/0 and merplus/0 redox couples in the high-resistance solvent dichloromethane, at microelectrodes, under both steady-state and fast scan...

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Bibliographic Details
Published in:Analytical chemistry (Washington) 1992-05, Vol.64 (9), p.1014
Main Authors: Bond, Alan M, Feldberg, Stephen W, Greenhill, Howard B, Mahon, Peter J
Format: Article
Language:English
Subjects:
Chemistry
Kinetics
Solvents
Thermodynamics
Online Access:Get full text
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Summary:Instrumental, experimental and theoretical approaches required to quantify the thermodynamic and kinetic aspects of the square reaction scheme relating the facplus/0 and merplus/0 redox couples in the high-resistance solvent dichloromethane, at microelectrodes, under both steady-state and fast scan rate (transient) conditions, are presented.
ISSN:0003-2700
1520-6882