Engineering robust metal–phenolic network membranes for uranium extraction from seawater

• Published in: Energy & environmental science 2019-02, Vol.12 (2), p.607-614
• Main Authors: Luo, Wei, Xiao, Gao, Tian, Fan, Richardson, Joseph J., Wang, Yaping, Zhou, Jianfei, Guo, Junling, Liao, Xuepin, Shi, Bi
• Format: Article
• Language: English
• Subjects: Antifouling substances; Chemical analysis; Competitiveness; Economic analysis; Field tests; Kinetics; Membranes; Metals; Nuclear energy; Oceans; Phenolic compounds; Phenols; Seawater; Selectivity; Sustainability; Uranium; Water analysis
• ISSN: 1754-5692; 1754-5706
• DOI: 10.1039/C8EE01438H

Roughly 4 billion tons of uranium exists in the oceans, which equates to a nearly inexhaustible supply for nuclear power production. However, the extraction of uranium from seawater is highly challenging due the background high salinity and uranium's relatively low concentration (∼3 μg L −1 ). Current approaches are generally limited by either their selectivity, sustainability, or their economic competitiveness. Here we engineered a biomass-derived microporous membrane, based on the interfacial formation of robust metal–phenolic networks (MPNs), for uranium capture from seawater. These membranes displayed advantages in terms of selectivity, kinetics, capacity, and renewability in both laboratory settings and marine field-testing. The MPN-based membranes showed a greater than ninefold higher uranium extraction capacity (27.81 μg) than conventional methods during a long-term cycling extraction of 10 L of natural seawater from the East China Sea. These results, coupled with our techno-economic analysis, demonstrate that MPN-based membranes are promising economically viable and industrially scalable materials for real-world uranium extraction.