Precipitation evolution in Cux[Ni3Cr1] spinodal alloys under mismatch control

• Published in: Materials chemistry and physics 2019-02, Vol.223, p.486-493
• Main Authors: Li, X.N., Li, Z.M., Cheng, X.T., Sun, W., Zheng, Y.H., Yu, Q.X., Wang, C.Y., Wang, Q., Dong, C.
• Format: Article
• Language: English
• Subjects: Alloy systems; Chemical precipitation; Copper; Copper alloy; Corrosion resistance; Decomposition; Evolution; Gamma-2 phase (crystals); Grain boundaries; Mechanical properties; Microstructure; Mismatch; Morphology; Nickel; Packing density; Precipitates; Solid solutions; Spinodal decomposition; Strengthening
• ISSN: 0254-0584; 1879-3312
• DOI: 10.1016/j.matchemphys.2018.11.035

CuNiCr alloys have a typical spinodal decomposition structure. However, a systematic investigation of the correlation between the mismatch of the two decomposition phases, Cu-rich (γ1) and Ni-rich (γ2), and the γ2 morphology is lacking. In this study, the microstructure evolution of Cux[Ni3Cr1] (x = 1, 2, 3, 4, 5, 7, 9, and 12) alloys was investigated over a wide composition range. The results show that mismatch significantly affects the shape of the γ2 precipitates. The γ2 phase is cubic when the mismatch degree (η) is in the range 0.62%–0.75% and lath-shaped when η is in the range 1.08%–1.35%. With increasing Cu content, the proportion of the lath-shaped γ2 phase decreases and that of the cubic γ2 phase continuously increases. Cubic precipitates enhance the alloy strength, while lath-shaped precipitates show better corrosion resistance owing to their high packing density. Therefore, an appropriate x can be chosen according to the actual service conditions. In addition, the Cr state affects the microstructure and performance of the alloys. Cr in the solid solution state promotes spinodal decomposition, while a large amount of Cr-rich precipitates at the grain boundaries has a negative effect on the mechanical performance. •Microstructure evolution of Cux[Ni3Cr1] alloys was investigated systematically.•The lattice mismatch (η) affects the shape of the γ2 phase.•Effect of the Cr state on the microstructure and properties of the alloys was studied.