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Microstructure variation in thick AlInN films grown on c-plane GaN on sapphire by metalorganic chemical vapor deposition
•300-nm-thick AlInN films were grown on GaN on sapphire by MOCVD.•AlInN surfaces drastically varied around a lattice-matching composition.•Optical constants and energy bandgaps were determined for flat-surface AlInN films. 300-nm-thick AlInN films with InN molar fractions ranging from 0.114 to 0.197...
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Published in: | Journal of crystal growth 2019-01, Vol.506, p.40-44 |
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container_title | Journal of crystal growth |
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creator | Miyoshi, Makoto Yamanaka, Mizuki Egawa, Takashi Takeuchi, Tetsuya |
description | •300-nm-thick AlInN films were grown on GaN on sapphire by MOCVD.•AlInN surfaces drastically varied around a lattice-matching composition.•Optical constants and energy bandgaps were determined for flat-surface AlInN films.
300-nm-thick AlInN films with InN molar fractions ranging from 0.114 to 0.197 were grown by metalorganic chemical vapor deposition on c-plane GaN on sapphire. It was confirmed that no lattice relaxation occurred for samples with InN molar fractions from 0.144 to 0.197, and the InAlN films with low InN molar fractions showed a relative smooth surface. However, it turned into a granular surface morphology resulting from a columnar polycrystalline structure when the InN molar fraction exceeded a compositional boundary of in-plane lattice matching. As for the smooth-surface AlInN single-layers, the optical constants as well as energy bandgaps were determined. |
doi_str_mv | 10.1016/j.jcrysgro.2018.09.049 |
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300-nm-thick AlInN films with InN molar fractions ranging from 0.114 to 0.197 were grown by metalorganic chemical vapor deposition on c-plane GaN on sapphire. It was confirmed that no lattice relaxation occurred for samples with InN molar fractions from 0.144 to 0.197, and the InAlN films with low InN molar fractions showed a relative smooth surface. However, it turned into a granular surface morphology resulting from a columnar polycrystalline structure when the InN molar fraction exceeded a compositional boundary of in-plane lattice matching. As for the smooth-surface AlInN single-layers, the optical constants as well as energy bandgaps were determined.</description><identifier>ISSN: 0022-0248</identifier><identifier>EISSN: 1873-5002</identifier><identifier>DOI: 10.1016/j.jcrysgro.2018.09.049</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>A1. Crystal morphology ; A3. Metalorganic vapor phase epitaxy ; B1. Nitrides ; B2. Semiconducting III-V materials ; B2. Semiconducting ternary compounds ; Chemical vapor deposition ; Columnar structure ; Lattice matching ; Metalorganic chemical vapor deposition ; Morphology ; Organic chemistry ; Sapphire ; Thick films</subject><ispartof>Journal of crystal growth, 2019-01, Vol.506, p.40-44</ispartof><rights>2018 Elsevier B.V.</rights><rights>Copyright Elsevier BV Jan 15, 2019</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c450t-46065acf394edad885c05c15b9850fb875c4d9db2bfe309479c578eefe880a393</citedby><cites>FETCH-LOGICAL-c450t-46065acf394edad885c05c15b9850fb875c4d9db2bfe309479c578eefe880a393</cites><orcidid>0000-0001-9583-1891</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Miyoshi, Makoto</creatorcontrib><creatorcontrib>Yamanaka, Mizuki</creatorcontrib><creatorcontrib>Egawa, Takashi</creatorcontrib><creatorcontrib>Takeuchi, Tetsuya</creatorcontrib><title>Microstructure variation in thick AlInN films grown on c-plane GaN on sapphire by metalorganic chemical vapor deposition</title><title>Journal of crystal growth</title><description>•300-nm-thick AlInN films were grown on GaN on sapphire by MOCVD.•AlInN surfaces drastically varied around a lattice-matching composition.•Optical constants and energy bandgaps were determined for flat-surface AlInN films.
300-nm-thick AlInN films with InN molar fractions ranging from 0.114 to 0.197 were grown by metalorganic chemical vapor deposition on c-plane GaN on sapphire. It was confirmed that no lattice relaxation occurred for samples with InN molar fractions from 0.144 to 0.197, and the InAlN films with low InN molar fractions showed a relative smooth surface. However, it turned into a granular surface morphology resulting from a columnar polycrystalline structure when the InN molar fraction exceeded a compositional boundary of in-plane lattice matching. As for the smooth-surface AlInN single-layers, the optical constants as well as energy bandgaps were determined.</description><subject>A1. Crystal morphology</subject><subject>A3. Metalorganic vapor phase epitaxy</subject><subject>B1. Nitrides</subject><subject>B2. Semiconducting III-V materials</subject><subject>B2. Semiconducting ternary compounds</subject><subject>Chemical vapor deposition</subject><subject>Columnar structure</subject><subject>Lattice matching</subject><subject>Metalorganic chemical vapor deposition</subject><subject>Morphology</subject><subject>Organic chemistry</subject><subject>Sapphire</subject><subject>Thick films</subject><issn>0022-0248</issn><issn>1873-5002</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNqFkEFv2zAMhYViA5p1_QuFgJ3tUrYVS7cVxZoF6LLLdhZkmm7kOpYnOd3y7ysj7XkXEgT53gM_xm4E5ALE-rbPewyn-BR8XoBQOegcKn3BVkLVZSYBig9slWqRQVGpS_Ypxh4gKQWs2L8fDoOPczjifAzEX2xwdnZ-5G7k897hM78btuOOd244RJ5C_o48bTGbBjsS39jdMkY7TXuX9M2JH2i2gw9PdnTIcU8Hh3ZIxpMPvKXJR7f4f2YfOztEun7rV-z3w7df99-zx5-b7f3dY4aVhDmr1rCWFrtSV9TaVimJIFHIRisJXaNqiVWr26ZoOipBV7VGWSuijpQCW-ryin05-07B_zlSnE3vj2FMkaYQStQyMVyu1uerBUYM1JkpuIMNJyPALJRNb94pm4WyAW0S5ST8ehZS-uHFUTARHY1IbaKBs2m9-5_FK3h9i7w</recordid><startdate>20190115</startdate><enddate>20190115</enddate><creator>Miyoshi, Makoto</creator><creator>Yamanaka, Mizuki</creator><creator>Egawa, Takashi</creator><creator>Takeuchi, Tetsuya</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0001-9583-1891</orcidid></search><sort><creationdate>20190115</creationdate><title>Microstructure variation in thick AlInN films grown on c-plane GaN on sapphire by metalorganic chemical vapor deposition</title><author>Miyoshi, Makoto ; Yamanaka, Mizuki ; Egawa, Takashi ; Takeuchi, Tetsuya</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c450t-46065acf394edad885c05c15b9850fb875c4d9db2bfe309479c578eefe880a393</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>A1. Crystal morphology</topic><topic>A3. Metalorganic vapor phase epitaxy</topic><topic>B1. Nitrides</topic><topic>B2. Semiconducting III-V materials</topic><topic>B2. Semiconducting ternary compounds</topic><topic>Chemical vapor deposition</topic><topic>Columnar structure</topic><topic>Lattice matching</topic><topic>Metalorganic chemical vapor deposition</topic><topic>Morphology</topic><topic>Organic chemistry</topic><topic>Sapphire</topic><topic>Thick films</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Miyoshi, Makoto</creatorcontrib><creatorcontrib>Yamanaka, Mizuki</creatorcontrib><creatorcontrib>Egawa, Takashi</creatorcontrib><creatorcontrib>Takeuchi, Tetsuya</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of crystal growth</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Miyoshi, Makoto</au><au>Yamanaka, Mizuki</au><au>Egawa, Takashi</au><au>Takeuchi, Tetsuya</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Microstructure variation in thick AlInN films grown on c-plane GaN on sapphire by metalorganic chemical vapor deposition</atitle><jtitle>Journal of crystal growth</jtitle><date>2019-01-15</date><risdate>2019</risdate><volume>506</volume><spage>40</spage><epage>44</epage><pages>40-44</pages><issn>0022-0248</issn><eissn>1873-5002</eissn><abstract>•300-nm-thick AlInN films were grown on GaN on sapphire by MOCVD.•AlInN surfaces drastically varied around a lattice-matching composition.•Optical constants and energy bandgaps were determined for flat-surface AlInN films.
300-nm-thick AlInN films with InN molar fractions ranging from 0.114 to 0.197 were grown by metalorganic chemical vapor deposition on c-plane GaN on sapphire. It was confirmed that no lattice relaxation occurred for samples with InN molar fractions from 0.144 to 0.197, and the InAlN films with low InN molar fractions showed a relative smooth surface. However, it turned into a granular surface morphology resulting from a columnar polycrystalline structure when the InN molar fraction exceeded a compositional boundary of in-plane lattice matching. As for the smooth-surface AlInN single-layers, the optical constants as well as energy bandgaps were determined.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jcrysgro.2018.09.049</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0001-9583-1891</orcidid><oa>free_for_read</oa></addata></record> |
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subjects | A1. Crystal morphology A3. Metalorganic vapor phase epitaxy B1. Nitrides B2. Semiconducting III-V materials B2. Semiconducting ternary compounds Chemical vapor deposition Columnar structure Lattice matching Metalorganic chemical vapor deposition Morphology Organic chemistry Sapphire Thick films |
title | Microstructure variation in thick AlInN films grown on c-plane GaN on sapphire by metalorganic chemical vapor deposition |
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