A new class of supramolecular liquid crystals derived from azo calix[4]arene functionalized 1,3,4-thiadiazole derivatives

A new class of bowl-shaped supramolecular liquid crystals (LCs) is described derived from calix[4]arene substituted with 1,3,4-thiadiazole derivatives, inbuilt with Schiff base and ester on the lower rim and with an azo group on the upper rim with an alkyl side chain (-OC 3 H 7 , -OC 8 H 17 ). In th...

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Bibliographic Details
Published in:New journal of chemistry 2019-02, Vol.43 (8), p.3556-3564
Main Authors: Sharma, Vinay S, Shah, Akshara P, Sharma, Anuj S
Format: Article
Language:English
Subjects:
Calixarenes
Chains
Derivatives
Differential scanning calorimetry
Fluorescence
High temperature
Imines
Liquid crystals
Optical microscopy
Phase transitions
Substitutes
Supramolecular compounds
Synthesis
Thermogravimetric analysis
Thiadiazoles
UV stabilizers
X-ray diffraction
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Summary:A new class of bowl-shaped supramolecular liquid crystals (LCs) is described derived from calix[4]arene substituted with 1,3,4-thiadiazole derivatives, inbuilt with Schiff base and ester on the lower rim and with an azo group on the upper rim with an alkyl side chain (-OC 3 H 7 , -OC 8 H 17 ). In the present investigation, we have synthesized six new supramolecular-based derivatives having three linking units with a substituted 1,3,4-thiadiazole ring and a variable trisubstituted side alkoxy chain on the lower rim of calix[4]arene. These supramolecular compounds were investigated by polarizing optical microscopy (POM), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and high temperature X-ray diffraction studies (XRD). All synthesized compounds exhibited good blue fluorescence in solution under long wavelength UV light. The present compounds are promising for stabilizing the hexagonal columnar phase over a broad thermal range. The bowl-shaped calixarene-based LCs pack into columns with enhanced intermolecular interactions. The liquid crystalline properties are influenced by the structures of the spacers on the calix[4]arene skeleton and enhance the phase transition temperatures. A new class of bowl-shaped supramolecular liquid crystals (LCs) is described derived from calix[4]arene substituted with 1,3,4-thiadiazole derivatives, inbuilt with Schiff base and ester on the lower rim and with an azo group on the upper rim with an alkyl side chain (-OC 3 H 7 , -OC 8 H 17 ).
ISSN:1144-0546
1369-9261
DOI:10.1039/c8nj04997a