Metal contact recombination in monoPoly™ solar cells with screen-printed & fire-through contacts

• Published in: Solar energy materials and solar cells 2019-04, Vol.192, p.109-116
• Main Authors: Padhamnath, Pradeep, Wong, Johnson, Nagarajan, Balaji, Buatis, Jammaal Kitz, Ortega, Luisa Ma, Nandakumar, Naomi, Khanna, Ankit, Shanmugam, Vinodh, Duttagupta, Shubham
• Format: Article
• Language: English
• Subjects: Contact-recombination; Doped poly-Silicon; Electrical resistivity; LPCVD; Metallizing; Metals; monoPoly; Open circuit voltage; Passivated contacts; Pastes; Phosphorus; Photoluminescence; Photons; Photovoltaic cells; Recombination; Screen printed; Solar cells
• ISSN: 0927-0248; 1879-3398
• DOI: 10.1016/j.solmat.2018.12.026

We present a detailed analysis of the contact properties with screen printed fire-through (FT) metal pastes on phosphorus doped (n+) polysilicon (poly-Si) layers. Two different pastes are evaluated for their contact resistivity and contact recombination on n+ doped poly-Si and on n+ doped c-Si. We present excellent contact resistivity (ρc) values ~ 1.5 mΩ-cm2 measured by the transfer length method (TLM) for metal contacts with doped poly-Si layer. The recombination at the metallized contacts is evaluated by analyzing the photoluminescence of the samples together with the Griddler software. In this work, we report ultra-low saturation current density values of 35 fA/cm2 under the metal contacts. We demonstrate that solar cells with a rear passivated contact show an average + 16 mV improvement in cell open circuit voltage as compared to the standard cells when using well-suited rear metal pastes. Efficiency of 21.8% is reported for cells printed with the best performing paste on large-area (244.3 cm2) commercially available n-type Czochralski grown Si wafers. [Display omitted] •Polysilicon-based passivated contacts result in higher cell voltages and efficiencies.•Excellent contact resistivity values of 1.5 mΩ-cm2 for screen-printed and fired contacts.•Ultra-low saturation current density values of 35 fA/cm2 under the metal contacts.•21.8% efficient screen printed and fired large area monoPoly™ solar cells.