Electrochemical Investigation of Some Pharmaceutical Compounds at Mercury Electrode

The present work aims to report the investigation of the electrochemical behavior of 3- arylazomethine-1,2,4-triazole derivatives in universal aqueous buffer series at mercury electrode. The electrode behavior of the studied compounds was performed via voltammetric studies, chronoamperometry, convol...

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Bibliographic Details
Published in:Oriental journal of chemistry 2018-01, Vol.34 (6), p.2851-2858
Main Authors: Al-Owais, A. A., El-Hallag, I. S.
Format: Article
Language:English
Subjects:
Aromatic compounds
Biological activity
Buffers
Derivatives
Digital simulation
Electrochemical analysis
Electrodes
Histamine
Investigations
Mercury
Organic chemistry
Organic light emitting diodes
Parameters
Phenols
Polarography
Triazoles
Voltammetry
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Summary:The present work aims to report the investigation of the electrochemical behavior of 3- arylazomethine-1,2,4-triazole derivatives in universal aqueous buffer series at mercury electrode. The electrode behavior of the studied compounds was performed via voltammetric studies, chronoamperometry, convoluted transforms, and dp polarography techniques. The relevant chemical and electrochemical parameters of 3- aryl azomethine -1,2,4- triazole derivatives were determined experimentally in universal aqueous buffer series as supporting electrolyte at mercury electrode. CPC was used for determination of the number of electrons to elucidate the mechanistic pathway of electrode reaction of aryl azomethine triazole compounds. Digital simulation method was used to confirm the accuracy of the experimental chemical parameters (homogeneous chemical rate constant) and electrochemical parameters (heterogeneous rate constant, symmetry coefficient and redox potential) via matching between the experimental and theoretical cyclic voltammograms.
ISSN:0970-020X
2231-5039
DOI:10.13005/ojc/340623