Frontispiece: Size Matters: From Two‐Dimensional AuI–TlI Metallopolymers to Molecular Complexes by Simple Variation of the Steric Demand

Au‐Tl metallopolymers of different dimensionalities and heterobimetallic backbones were synthesized by using bis(acetylido)aurates(I) and thallium(I) trifluoromethylsulfonates. Their corresponding metal scaffolds are shown as a blue‐luminescent two‐dimensional framework (background), a one‐dimension...

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Bibliographic Details
Published in:Chemistry : a European journal 2019-03, Vol.25 (15), p.n/a
Main Authors: Seifert, Tim P., Knoefel, Nicolai D., Feuerstein, Thomas J., Reiter, Kevin, Lebedkin, Sergei, Gamer, Michael T., Boukis, Andreas C., Weigend, Florian, Kappes, Manfred M., Roesky, Peter W.
Format: Article
Language:English
Subjects:
Chemistry
dimensional control
gold
Irradiation
luminescence
metallophilicity
Thallium
Ultraviolet radiation
Visible spectrum
Online Access:Get full text
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Summary:Au‐Tl metallopolymers of different dimensionalities and heterobimetallic backbones were synthesized by using bis(acetylido)aurates(I) and thallium(I) trifluoromethylsulfonates. Their corresponding metal scaffolds are shown as a blue‐luminescent two‐dimensional framework (background), a one‐dimensional chain and a discrete cluster emitting in the yellow region of the visible spectrum (front). Furthermore, the luminescent samples are displayed under UV irradiation. For more information see Full Paper by P. W. Roesky et al. on page 3799 ff.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201981565