Mechanism of high temperature induced phase transformation and magnetic properties of Mn3O4 crystallites

• Published in: Journal of magnetism and magnetic materials 2019-04, Vol.476, p.268-273
• Main Authors: Narayani, Lakshmi, Jagadeesha Angadi, V., Sukhdev, Anu, Challa, Malathi, Matteppanavar, Shidaling, Deepthi, P.R., Mohan Kumar, P., Pasha, Mehaboob
• Format: Article
• Language: English
• Subjects: Bixbyite; Coercivity; Crystallites; Ferrimagnetism; Ferromagnetism; Glucose; Hausmannite-phase transition; Heat treatment; High temperature; Magnetic fields; Magnetic measurement; Magnetic permeability; Magnetic properties; Magnetic transitions; Magnetism; Manganese oxides; Morphology; Phase transitions; Raman spectroscopy; Remanence; Scanning electron microscopy; Sintering (powder metallurgy); Solution combustion synthesis; Susceptibility; Temperature; Temperature dependence; Thermal stability; Urea; X ray powder diffraction; X-ray diffraction
• ISSN: 0304-8853; 1873-4766
• DOI: 10.1016/j.jmmm.2018.12.072

•Different phases of oxides of manganese, prepared by solution combustion method using urea and glucose as fuels.•Mn2O3 is stable between temperatures of 350 °C and 850 °C, and a new phase i.e Mn3O4 appears at 1000 °C.•The Mn3O4 crystallite with diameters of 50 nm shows ferromagnetic behavior with a phase transition from ferromagnetic to paramagnetic phase at 48 K.•The susceptibility measurement of the Mn3O4 crystallites were investigated between 0 and 300 K and a magnetic transition is observed near 48 K. This paper is an experimental study of the different phases of oxides of manganese, prepared by solution combustion method using mixture of urea and glucose as fuels. To validate the thermal stability of Mn2O3, the as-synthesized sample was subjected to heat treatment from 350 °C to 1000 °C with 100 °C interval. The change in Mn2O3 to Mn3O4 was identified by powder X-ray diffraction (PXRD) to show the temperature dependent phase transformation that occur during the heat treatment process. The PXRD patterns show that Mn2O3 is stable between temperatures of 350 °C to 850 °C, and a new phase i.e Mn3O4 appears at 1000 °C. The Mn2O3 and Mn3O4 have their distinct surface morphologies viz., spherical and rod shapes. The detailed morphology, elemental compositions and structure investigation were carried out by using Scanning Electron Microscopy (SEM-EDAX) and Raman spectroscopy. Sintered sample of Mn3O4 were subjected to magnetic measurements. The Mn3O4 crystallite with diameters of 50 nm shows ferromagnetic behavior with a phase transition from ferromagnetic to paramagnetic phase at 48 K. A large coercivity up to 3000 Oe and a small remanence of 0.1092 emu/g at 10 K, was observed. The temperature dependent magnetization measured in a magnetic field of 100 Oe, increases significantly with decreasing temperature around 45 K, both for the FC and ZFC measurements. The susceptibility measurement of the Mn3O4 crystallites were investigated between 0 and 300 K by applied magnetic fields up to 5 T. A magnetic transition is observed near 48 K which is attributed to the formation of the ferrimagnetic Mn3O4.