Preparation of Near-Infrared (NIR) Reflective Pigment by Solid State Reaction between Fe2O3 and Al2O3

• Published in: Key engineering materials 2018-04, Vol.766, p.127-132
• Main Authors: Khongwong, Wasana, Busabok, Chumphol, Ngernchuklin, Piyalak, Kanchanasutha, Sittichai, Somwongsa, Phunthinee, Saensing, Arunrat
• Format: Article
• Language: English
• Subjects: Aluminum oxide; Ball milling; Metal sheets; Protective coatings; Roasting; Spinel; Temperature; Temperature gradients
• ISSN: 1013-9826; 1662-9795; 1662-9795
• DOI: 10.4028/www.scientific.net/KEM.766.127

Reflective pigment was prepared by using Fe2O3 and Al2O3 as starting materials. Fe2O3 and Al2O3 powders were mixed at 0.8:2, 1:2 and 1.2:2 mole ratio using ball milling. The mixed powders were dried and calcined at temperature of 1500°C, 1600°C and 1700°C for various soaking time at 2, 8 and 20 h. Phase data were analyzed by x-ray diffractometry. It was found that (Al1-x, Fex)2O3 presented as a new phase in calcined powders at temperature of 1500°C to 1700°C for 2 h. The other new phase such as FeAl2O4 was detected in calcined powders at temperature of 1700°C for 8 and 20 h. From the experimental results indicated that complete reaction was occurred when higher calcination temperature and longer soaking time were used, resulting in spinel structure (FeAl2O4) generated. Then, the synthesized powders were mixed with exterior paint by mass ratio of 0:100, 10:90, 20:80, 30:70 and 40:60, respectively. The mixed paints were sprayed on metal sheets. Then the coated metal sheets were exposed under 200 watts lamb and measured the temperature difference between the exposed side and opposite side. The result showed that at the ratio of 30:70 exhibited the highest temperature difference of 14°C approximately. From the result, we concluded that spinel structure (FeAl2O4) is a candidate for near-infrared (NIR) reflective pigment of exterior paint.