Anodic Titanium Oxide Layers Modified with Gold, Silver, and Copper Nanoparticles

Titanium(IV) oxide is commonly used in photocatalysis. However, it has some drawbacks, e.g., a high rate of electron-hole recombination and a wide bandgap. In here, the surface of anodic titanium(IV) oxide (ATO) was modified with metal nanoparticles (gold, silver, and copper) in order to enhance its...

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Bibliographic Details
Published in:Journal of nanomaterials 2019-01, Vol.2019 (2019), p.1-10
Main Authors: Brudzisz, Anna, Sennik-Kubiec, Aneta, Grudzień, Joanna, Syrek, Karolina, Sulka, Grzegorz D.
Format: Article
Language:English
Subjects:
Copper
Current efficiency
Decomposition reactions
Efficiency
Electrolytes
Gold
Holes (electron deficiencies)
Metals
Nanomaterials
Nanoparticles
Organic chemistry
Photocatalysis
Photodecomposition
Silver
Titanium
Titanium dioxide
Titanium oxides
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Summary:Titanium(IV) oxide is commonly used in photocatalysis. However, it has some drawbacks, e.g., a high rate of electron-hole recombination and a wide bandgap. In here, the surface of anodic titanium(IV) oxide (ATO) was modified with metal nanoparticles (gold, silver, and copper) in order to enhance its photoelectrochemical (PEC) and photocatalytic (PC) properties. SEM analysis revealed that Au, Ag, and Cu nanoparticles obtained on an ATO surface by chemical methods had an average diameter of 50 ± 10 nm, 30 ± 6 nm, and 25 ± 3 nm, respectively. Enhancement of photoelectrochemical water-splitting current efficiency in the wavelength range of 300–400 nm was observed due to the occurrence of the Schottky barriers. However, the nanoparticles had no effect on the current efficiency in the range of 400–600 nm which meant that the surface plasmon resonance (SPR) effect was not observed. A rate of methyl red photodecomposition was improved after the modification of the ATO surface. The best results were obtained for ATO decorated with gold nanoparticles.
ISSN:1687-4110
1687-4129
DOI:10.1155/2019/9208734