Synthesis of a ZIF-derived hollow yolk-shell Co@CN catalyst for the oxidative esterification of 5-hydroxymethylfurfural

A newly developed template protection-sacrifice (TPS) strategy is developed for the synthesis of hollow yolk-shell Co@CN with a large surface area and high pore volume. The catalyst exhibits excellent catalytic efficiency in base-free oxidative esterification of 5-hydroxymethylfurfural under mild co...

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Published in:Green chemistry : an international journal and green chemistry resource : GC 2019, Vol.21 (7), p.162-168
Main Authors: Sun, Kang-kang, Chen, Shu-jie, Li, Ze-lin, Lu, Guo-ping, Cai, Chun
Format: Article
Language:English
Subjects:
Catalysis
Catalysts
Chemical synthesis
EGR-1 protein
Esterification
Green chemistry
Hydroxymethylfurfural
Selectivity
Yolk
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description A newly developed template protection-sacrifice (TPS) strategy is developed for the synthesis of hollow yolk-shell Co@CN with a large surface area and high pore volume. The catalyst exhibits excellent catalytic efficiency in base-free oxidative esterification of 5-hydroxymethylfurfural under mild conditions with excellent selectivity at a high concentration (2 M) of the reactant. A ZIF-derived hollow yolk-shell Co@CN catalyst is synthesized for the oxidative esterification of 5-hydroxymethylfurfural.
doi_str_mv 10.1039/c8gc03868f
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subjects Catalysis
Catalysts
Chemical synthesis
EGR-1 protein
Esterification
Green chemistry
Hydroxymethylfurfural
Selectivity
Yolk
title Synthesis of a ZIF-derived hollow yolk-shell Co@CN catalyst for the oxidative esterification of 5-hydroxymethylfurfural
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