Progress in the synthesis of perylene bisimide dyes

With their versatile absorption, fluorescence, n-type semiconducting and (photo-)stability properties, perylene bisimides have evolved as the most investigated compounds among polycyclic aromatic hydrocarbons during the last decade. In this review we collect the results from about 200 original publi...

Full description

Saved in:
Bibliographic Details
Published in:Organic chemistry frontiers an international journal of organic chemistry 2019-04, Vol.6 (8), p.1272-1318
Main Authors: Nowak-Król, Agnieszka, Würthner, Frank
Format: Article
Language:English
Subjects:
Aromatic compounds
Carbonyl groups
Carbonyls
Chemical reactions
Dyes
Fluorescence
N-type semiconductors
Oligomers
Optical properties
Organic chemistry
Polycyclic aromatic hydrocarbons
Citations: Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:With their versatile absorption, fluorescence, n-type semiconducting and (photo-)stability properties, perylene bisimides have evolved as the most investigated compounds among polycyclic aromatic hydrocarbons during the last decade. In this review we collect the results from about 200 original publications, reporting a plethora of new perylene bisimide derivatives whose properties widely enrich the possibility for the application of these dyes beyond traditional fields. While some applications are highlighted, different from other recent reviews, our focus here is on the advances in the synthetic methodologies that have afforded new bay functionalizations, recently addressed functionalizations at the ortho-positions to the carbonyl groups, and annulation of carbo- and heterocyclic units. An impressive number of perylene bisimide oligomers are highlighted as well which are connected by single bonds or spiro linkage or in a fused manner, leading to arrays with fascinating optical and electronic properties.
ISSN:2052-4110
2052-4110
DOI:10.1039/c8qo01368c