Phosphorus-Doped Carbon Composites with Rich Graphene Derived from Phenol Resin as Supercapacitor Electrode Materials with High Window Potential and Energy Density

• Published in: Journal of electronic materials 2019-07, Vol.48 (7), p.4196-4206
• Main Authors: Zhang, Jianyu, Ali, Sikander, Liu, Fugui, Ali, Ahmad, Wang, Kang, Wang, Xitao
• Format: Article
• Language: English
• Subjects: Aqueous electrolytes; Capacitance; Carbon; Characterization and Evaluation of Materials; Chemistry and Materials Science; Electrochemical analysis; Electrode materials; Electrodes; Electronics and Microelectronics; Flux density; Fourier transforms; Graphene; Instrumentation; Mapping; Materials Science; Microscopy; Molten salts; Morphology; Optical and Electronic Materials; Phosphorus; Photoelectrons; Polymer matrix composites; Raman spectroscopy; Scanning electron microscopy; Solid State Physics; Spectrum analysis; Supercapacitors; Transmission electron microscopy; X-ray diffraction
• ISSN: 0361-5235; 1543-186X
• DOI: 10.1007/s11664-019-07188-5

We reported a simple one-step way for synthesizing phosphorus-doped (P-doped) carbon composites with rich graphene (P-CCG) in this study. We prepared P-CCG in the presence of KCl molten salt at 750°C by using soluble phenolic resole and triphenylphosphine as carbon and phosphorus resources, respectively. Using x-ray photoelectron spectroscopy and elemental mapping, we detected the existence of P while the structure and morphology of P-CCG were analyzed by x-ray diffraction, transmission electron microscopy, scanning electron microscopy, Fourier transform infrared spectroscopy, and Raman spectroscopy. The morphology of P-CCG displayed that where scattered porous carbons exist, the graphene sheets chiefly constituted the composites. To further inquire into the influence of P doping, the electrochemical properties of P-CCG were tested by using P-CCG as the electrode material of button-type supercapacitors whose aqueous electrolyte was 6 M KOH. The results suggested P-CCG showed great improvements such as higher specific capacitance and strengthened cycling stability after 5000 cycles, compared with undoped carbon composites. The ideal sample, P0.4-CCG, offered outstanding capacitive behavior, including a larger specific capacitance of 277 F g −1 , wide voltage window of 1.6 V and, a higher energy density of 26.42 Wh kg −1 .