Surface modification of banana fibers using organosilanes: an IGC insight

• Published in: Cellulose (London) 2019-04, Vol.26 (6), p.3643-3654
• Main Authors: Alonso, Emanuel, Pothan, Laly A., Ferreira, Artur, Cordeiro, Nereida
• Format: Article
• Language: English
• Subjects: Adhesion tests; Agricultural wastes; Bioorganic Chemistry; Cell adhesion; Cell adhesion & migration; Cellulose; Cellulose fibers; Ceramics; Chemistry; Chemistry and Materials Science; Composites; Functional groups; Gas chromatography; Glass; Inverse gas chromatography; Morphology; Natural Materials; Organic Chemistry; Original Research; Physical Chemistry; Polymer Sciences; Porosity; Proteins; Sustainable Development
• ISSN: 0969-0239; 1572-882X
• DOI: 10.1007/s10570-019-02329-9

Banana fibers are an agricultural waste material with a great exploitation potential due to their cellulose-rich content. Raw banana fibers (RBF) were treated with 3-aminopropyltriethoxy silane and glycidoxypropyltrimethoxy silane to improve the inherent limitations of banana fibers, namely its poor cell adhesion. The fibers’ modification was evaluated by inverse gas chromatography (IGC). Similar γ s d values were observed between the RBF and silane-treated fibers (39–41 mJ/m 2 ), which indicates similar reactivity towards apolar probes. However, the decrease in the entropic parameter indicates the silane covalent bonding with the cellulose chains making a stiffer structure. Organosilane grafting was confirmed by an increased basic character in the silane-treated fibers ( K b / K a from 1.03 to 2.81). The surface morphology also changed towards higher contact area ( S BET increases 6.7 times) and porosity ( Dp increases up to 67%). Both morphological and functional group reactivity changes suggest that the organosilane treatment offers new opportunities for these fibers to be used as adsorbents for proteins as well as to cell adhesion. Therefore, IGC proved a simple and viable technique in the characterization of silane-treated fibers. Graphical abstract