Frontispiece: A Novel Cathode Material for Cathodic Dehalogenation of 1,1-Dibromo Cyclopropane Derivatives

Pharmaceutical Electrochemistry. The electrochemical dehalogenation represents a powerful and sustainable tool for the synthesis of pharmaceutically relevant cyclopropane building blocks in excellent yield. The key to the conversion is the leaded bronze cathode instead of traditional lead. This nove...

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Published in:Chemistry : a European journal 2015-09, Vol.21 (40), p.n/a
Main Authors: Gütz, Christoph, Selt, Maximilian, Bänziger, Markus, Bucher, Christoph, Römelt, Christina, Hecken, Nadine, Gallou, Fabrice, Galvão, Tomás R., Waldvogel, Siegfried R.
Format: Article
Language:English
Subjects:
Cathodes
Chemistry
Contamination
Corrosion products
Cyclopropane
cyclopropanes
Dehalogenation
electrochemical reduction
Electrochemistry
Electrode materials
Electrolysis
Heavy metals
leaded bronze
Leaded bronzes
Plasma
sustainable chemistry
Workers
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container_issue 40
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container_title Chemistry : a European journal
container_volume 21
creator Gütz, Christoph
Selt, Maximilian
Bänziger, Markus
Bucher, Christoph
Römelt, Christina
Hecken, Nadine
Gallou, Fabrice
Galvão, Tomás R.
Waldvogel, Siegfried R.
description Pharmaceutical Electrochemistry. The electrochemical dehalogenation represents a powerful and sustainable tool for the synthesis of pharmaceutically relevant cyclopropane building blocks in excellent yield. The key to the conversion is the leaded bronze cathode instead of traditional lead. This novel cathode material is less prone to corrosion and provides highly pure product. Thereby, contamination by heavy metal traces is tremendously reduced. Furthermore, by slightly switching the electrolysis conditions, selective mono‐ or twofold dehalogenation is achieved. For more details, see the Communication by S. R. Waldvogel and co‐workers on page 13878 ff.
doi_str_mv 10.1002/chem.201584061
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subjects Cathodes
Chemistry
Contamination
Corrosion products
Cyclopropane
cyclopropanes
Dehalogenation
electrochemical reduction
Electrochemistry
Electrode materials
Electrolysis
Heavy metals
leaded bronze
Leaded bronzes
Plasma
sustainable chemistry
Workers
title Frontispiece: A Novel Cathode Material for Cathodic Dehalogenation of 1,1-Dibromo Cyclopropane Derivatives
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