Control of molecular orientation in a single-molecule junction with a tripodal triptycene anchoring unit: toward a simple and facile single-molecule diode

We report a simple and facile procedure to control molecular orientation in a single-molecule junction and relevant rectification properties. Rectification properties of single-molecule junctions consisting of tripodal triptycene and C60 moieties at the termini that couple to the Au electrodes were...

Full description

Saved in:
Bibliographic Details
Published in:Japanese Journal of Applied Physics 2019-03, Vol.58 (3), p.35003
Main Authors: Fujii, Shintaro, Ishiwari, Fumitaka, Komoto, Yuki, Su, Lixinzhu, Yamagata, Yuto, Kosaka, Atsuko, Aiba, Akira, Nishino, Tomoaki, Fukushima, Takanori, Kiguchi, Manabu
Format: Article
Language:English
Subjects:
Anchoring
Buckminsterfullerene
Electrodes
Fullerenes
Orientation
Statistical analysis
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c385t-3b46fad0ed842d09ad3d0c55fbef859b93883a317a10ccc8a0ea2af9dd85681b3
cites cdi_FETCH-LOGICAL-c385t-3b46fad0ed842d09ad3d0c55fbef859b93883a317a10ccc8a0ea2af9dd85681b3
container_end_page
container_issue 3
container_start_page 35003
container_title Japanese Journal of Applied Physics
container_volume 58
creator Fujii, Shintaro
Ishiwari, Fumitaka
Komoto, Yuki
Su, Lixinzhu
Yamagata, Yuto
Kosaka, Atsuko
Aiba, Akira
Nishino, Tomoaki
Fukushima, Takanori
Kiguchi, Manabu
description We report a simple and facile procedure to control molecular orientation in a single-molecule junction and relevant rectification properties. Rectification properties of single-molecule junctions consisting of tripodal triptycene and C60 moieties at the termini that couple to the Au electrodes were determined using the break junction method. Because of the strong affinity of the tripodal triptycene moiety to the Au electrode, the molecular orientation and the related rectification direction are uniquely determined. Statistical analysis of the I-V curves of the single-molecule diode reveals the robustness of the rectification behavior with a statistically significant rectification ratio of 1.7.
doi_str_mv 10.7567/1347-4065/ab0436
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2213145400</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2213145400</sourcerecordid><originalsourceid>FETCH-LOGICAL-c385t-3b46fad0ed842d09ad3d0c55fbef859b93883a317a10ccc8a0ea2af9dd85681b3</originalsourceid><addsrcrecordid>eNp1kU1r3DAQhkVpodtt7jkKesmhTiRL8sq9laVNAgu5tGcx1sdGxiu5skzIX8mvjfaDFEJy0kjvM49gBqFzSi5XolldUcZXFSeNuIKOcNZ8QIuXp49oQUhNK97W9Wf0ZZr6cm0Epwv0tI4hpzjg6PAuDlbPAyQck7chQ_YxYB8w4MmH7WCrE2FxPwd9SB98vi95Tn6MBoZDkR-1DRZD0PdFFLZ4Dj7_wDk-QDIH2W4c9rnBDrQv5Wu98dHYr-iTg2GyZ6dzif7-_vVnfVNt7q5v1z83lWZS5Ip1vHFgiDWS14a0YJghWgjXWSdF27VMSgaMroASrbUEYqEG1xojRSNpx5bo29E7pvhvtlNWfZxTKF-quqaMcsEJKRQ5UjrFaUrWqTH5HaRHRYnab0Dtx63241bHDZSWi2OLj-N_Z9_DqIRUTBEmiliNxhX0-xvou-Zn8USYYg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2213145400</pqid></control><display><type>article</type><title>Control of molecular orientation in a single-molecule junction with a tripodal triptycene anchoring unit: toward a simple and facile single-molecule diode</title><source>Institute of Physics IOPscience extra</source><source>Institute of Physics:Jisc Collections:IOP Publishing Read and Publish 2024-2025 (Reading List)</source><creator>Fujii, Shintaro ; Ishiwari, Fumitaka ; Komoto, Yuki ; Su, Lixinzhu ; Yamagata, Yuto ; Kosaka, Atsuko ; Aiba, Akira ; Nishino, Tomoaki ; Fukushima, Takanori ; Kiguchi, Manabu</creator><creatorcontrib>Fujii, Shintaro ; Ishiwari, Fumitaka ; Komoto, Yuki ; Su, Lixinzhu ; Yamagata, Yuto ; Kosaka, Atsuko ; Aiba, Akira ; Nishino, Tomoaki ; Fukushima, Takanori ; Kiguchi, Manabu</creatorcontrib><description>We report a simple and facile procedure to control molecular orientation in a single-molecule junction and relevant rectification properties. Rectification properties of single-molecule junctions consisting of tripodal triptycene and C60 moieties at the termini that couple to the Au electrodes were determined using the break junction method. Because of the strong affinity of the tripodal triptycene moiety to the Au electrode, the molecular orientation and the related rectification direction are uniquely determined. Statistical analysis of the I-V curves of the single-molecule diode reveals the robustness of the rectification behavior with a statistically significant rectification ratio of 1.7.</description><identifier>ISSN: 0021-4922</identifier><identifier>EISSN: 1347-4065</identifier><identifier>DOI: 10.7567/1347-4065/ab0436</identifier><identifier>CODEN: JJAPB6</identifier><language>eng</language><publisher>Tokyo: IOP Publishing</publisher><subject>Anchoring ; Buckminsterfullerene ; Electrodes ; Fullerenes ; Orientation ; Statistical analysis</subject><ispartof>Japanese Journal of Applied Physics, 2019-03, Vol.58 (3), p.35003</ispartof><rights>2019 The Japan Society of Applied Physics</rights><rights>Copyright Japanese Journal of Applied Physics Mar 1, 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c385t-3b46fad0ed842d09ad3d0c55fbef859b93883a317a10ccc8a0ea2af9dd85681b3</citedby><cites>FETCH-LOGICAL-c385t-3b46fad0ed842d09ad3d0c55fbef859b93883a317a10ccc8a0ea2af9dd85681b3</cites><orcidid>0000-0003-2869-7674</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://iopscience.iop.org/article/10.7567/1347-4065/ab0436/pdf$$EPDF$$P50$$Giop$$H</linktopdf><link.rule.ids>314,780,784,27924,27925,38868,53840</link.rule.ids></links><search><creatorcontrib>Fujii, Shintaro</creatorcontrib><creatorcontrib>Ishiwari, Fumitaka</creatorcontrib><creatorcontrib>Komoto, Yuki</creatorcontrib><creatorcontrib>Su, Lixinzhu</creatorcontrib><creatorcontrib>Yamagata, Yuto</creatorcontrib><creatorcontrib>Kosaka, Atsuko</creatorcontrib><creatorcontrib>Aiba, Akira</creatorcontrib><creatorcontrib>Nishino, Tomoaki</creatorcontrib><creatorcontrib>Fukushima, Takanori</creatorcontrib><creatorcontrib>Kiguchi, Manabu</creatorcontrib><title>Control of molecular orientation in a single-molecule junction with a tripodal triptycene anchoring unit: toward a simple and facile single-molecule diode</title><title>Japanese Journal of Applied Physics</title><addtitle>Jpn. J. Appl. Phys</addtitle><description>We report a simple and facile procedure to control molecular orientation in a single-molecule junction and relevant rectification properties. Rectification properties of single-molecule junctions consisting of tripodal triptycene and C60 moieties at the termini that couple to the Au electrodes were determined using the break junction method. Because of the strong affinity of the tripodal triptycene moiety to the Au electrode, the molecular orientation and the related rectification direction are uniquely determined. Statistical analysis of the I-V curves of the single-molecule diode reveals the robustness of the rectification behavior with a statistically significant rectification ratio of 1.7.</description><subject>Anchoring</subject><subject>Buckminsterfullerene</subject><subject>Electrodes</subject><subject>Fullerenes</subject><subject>Orientation</subject><subject>Statistical analysis</subject><issn>0021-4922</issn><issn>1347-4065</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1kU1r3DAQhkVpodtt7jkKesmhTiRL8sq9laVNAgu5tGcx1sdGxiu5skzIX8mvjfaDFEJy0kjvM49gBqFzSi5XolldUcZXFSeNuIKOcNZ8QIuXp49oQUhNK97W9Wf0ZZr6cm0Epwv0tI4hpzjg6PAuDlbPAyQck7chQ_YxYB8w4MmH7WCrE2FxPwd9SB98vi95Tn6MBoZDkR-1DRZD0PdFFLZ4Dj7_wDk-QDIH2W4c9rnBDrQv5Wu98dHYr-iTg2GyZ6dzif7-_vVnfVNt7q5v1z83lWZS5Ip1vHFgiDWS14a0YJghWgjXWSdF27VMSgaMroASrbUEYqEG1xojRSNpx5bo29E7pvhvtlNWfZxTKF-quqaMcsEJKRQ5UjrFaUrWqTH5HaRHRYnab0Dtx63241bHDZSWi2OLj-N_Z9_DqIRUTBEmiliNxhX0-xvou-Zn8USYYg</recordid><startdate>20190301</startdate><enddate>20190301</enddate><creator>Fujii, Shintaro</creator><creator>Ishiwari, Fumitaka</creator><creator>Komoto, Yuki</creator><creator>Su, Lixinzhu</creator><creator>Yamagata, Yuto</creator><creator>Kosaka, Atsuko</creator><creator>Aiba, Akira</creator><creator>Nishino, Tomoaki</creator><creator>Fukushima, Takanori</creator><creator>Kiguchi, Manabu</creator><general>IOP Publishing</general><general>Japanese Journal of Applied Physics</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0003-2869-7674</orcidid></search><sort><creationdate>20190301</creationdate><title>Control of molecular orientation in a single-molecule junction with a tripodal triptycene anchoring unit: toward a simple and facile single-molecule diode</title><author>Fujii, Shintaro ; Ishiwari, Fumitaka ; Komoto, Yuki ; Su, Lixinzhu ; Yamagata, Yuto ; Kosaka, Atsuko ; Aiba, Akira ; Nishino, Tomoaki ; Fukushima, Takanori ; Kiguchi, Manabu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c385t-3b46fad0ed842d09ad3d0c55fbef859b93883a317a10ccc8a0ea2af9dd85681b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Anchoring</topic><topic>Buckminsterfullerene</topic><topic>Electrodes</topic><topic>Fullerenes</topic><topic>Orientation</topic><topic>Statistical analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fujii, Shintaro</creatorcontrib><creatorcontrib>Ishiwari, Fumitaka</creatorcontrib><creatorcontrib>Komoto, Yuki</creatorcontrib><creatorcontrib>Su, Lixinzhu</creatorcontrib><creatorcontrib>Yamagata, Yuto</creatorcontrib><creatorcontrib>Kosaka, Atsuko</creatorcontrib><creatorcontrib>Aiba, Akira</creatorcontrib><creatorcontrib>Nishino, Tomoaki</creatorcontrib><creatorcontrib>Fukushima, Takanori</creatorcontrib><creatorcontrib>Kiguchi, Manabu</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Japanese Journal of Applied Physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fujii, Shintaro</au><au>Ishiwari, Fumitaka</au><au>Komoto, Yuki</au><au>Su, Lixinzhu</au><au>Yamagata, Yuto</au><au>Kosaka, Atsuko</au><au>Aiba, Akira</au><au>Nishino, Tomoaki</au><au>Fukushima, Takanori</au><au>Kiguchi, Manabu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Control of molecular orientation in a single-molecule junction with a tripodal triptycene anchoring unit: toward a simple and facile single-molecule diode</atitle><jtitle>Japanese Journal of Applied Physics</jtitle><addtitle>Jpn. J. Appl. Phys</addtitle><date>2019-03-01</date><risdate>2019</risdate><volume>58</volume><issue>3</issue><spage>35003</spage><pages>35003-</pages><issn>0021-4922</issn><eissn>1347-4065</eissn><coden>JJAPB6</coden><abstract>We report a simple and facile procedure to control molecular orientation in a single-molecule junction and relevant rectification properties. Rectification properties of single-molecule junctions consisting of tripodal triptycene and C60 moieties at the termini that couple to the Au electrodes were determined using the break junction method. Because of the strong affinity of the tripodal triptycene moiety to the Au electrode, the molecular orientation and the related rectification direction are uniquely determined. Statistical analysis of the I-V curves of the single-molecule diode reveals the robustness of the rectification behavior with a statistically significant rectification ratio of 1.7.</abstract><cop>Tokyo</cop><pub>IOP Publishing</pub><doi>10.7567/1347-4065/ab0436</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0003-2869-7674</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 0021-4922
ispartof Japanese Journal of Applied Physics, 2019-03, Vol.58 (3), p.35003
issn 0021-4922
1347-4065
language eng
recordid cdi_proquest_journals_2213145400
source Institute of Physics IOPscience extra; Institute of Physics:Jisc Collections:IOP Publishing Read and Publish 2024-2025 (Reading List)
subjects Anchoring
Buckminsterfullerene
Electrodes
Fullerenes
Orientation
Statistical analysis
title Control of molecular orientation in a single-molecule junction with a tripodal triptycene anchoring unit: toward a simple and facile single-molecule diode
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-26T00%3A05%3A49IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Control%20of%20molecular%20orientation%20in%20a%20single-molecule%20junction%20with%20a%20tripodal%20triptycene%20anchoring%20unit:%20toward%20a%20simple%20and%20facile%20single-molecule%20diode&rft.jtitle=Japanese%20Journal%20of%20Applied%20Physics&rft.au=Fujii,%20Shintaro&rft.date=2019-03-01&rft.volume=58&rft.issue=3&rft.spage=35003&rft.pages=35003-&rft.issn=0021-4922&rft.eissn=1347-4065&rft.coden=JJAPB6&rft_id=info:doi/10.7567/1347-4065/ab0436&rft_dat=%3Cproquest_cross%3E2213145400%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c385t-3b46fad0ed842d09ad3d0c55fbef859b93883a317a10ccc8a0ea2af9dd85681b3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2213145400&rft_id=info:pmid/&rfr_iscdi=true