Combination of Pd loading and electron beam irradiation for superior hydrogen sensing of electrospun ZnO nanofibers

• Published in: Sensors and actuators. B, Chemical Chemical, 2019-04, Vol.284, p.628-637
• Main Authors: Kim, Jae-Hun, Mirzaei, Ali, Woo Kim, Hyoun, Kim, Sang Sub
• Format: Article
• Language: English
• Subjects: Catalysis; Catalytic activity; Clean energy; Detection; Electron beam irradiation; Electron beams; Electron irradiation; Fossil fuels; Gas sensors; Heterojunctions; Hydrogen; Metallizing; Nanofibers; Pd nanoparticles; Sensors; Zinc oxide; ZnO nanofibers
• ISSN: 0925-4005; 1873-3077
• DOI: 10.1016/j.snb.2018.12.120

•We investigated the hydrogen sensing of Pd-loaded ZnO nanofibers in regard to the effect of e-beam irradiation.•We optimized the sensing condition in terms of amount of Pd loading and e-beam irradiation dose.•The optimized sensor irradiated with 150 kGy had the high response (Ra/Rg) of 74.7 under 100 ppb of H2. We evaluated the hydrogen gas-sensing characteristics of Pd-loaded (0.1, 0.3, 0.6, and 1 wt%) ZnO nanofibers prepared by a facile electrospinning technique and the effect of different electron beam (e-beam) doses (50, 100, and 150 kGy) on sensing performance. The sensor loaded with 0.6 wt% Pd had the highest response to hydrogen among the Pd-loaded sensors. The sensor irradiated with 150 kGy had the high response (Ra/Rg) of 74.7–100 ppb of H2 at 350 °C. Metallization effects in ZnO, the formation of structural defects due to e-beam irradiation, the catalytic activity of Pd, and the presence of ZnO–Pd heterojunctions were the main factors yielding high sensitivity towards H2. The strategy of combining e-beam irradiation and Pd loading to enhance H2 sensing can be applied to realize reliable gas sensors and the widespread use of hydrogen as a green energy alternative to fossil fuels.