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A Zinc Coordination Polymer Assembled from bis(4-(1H-Imidazol-1-yl)Phenyl)Methanone and Phthalic Acid: Synthesis, Structural Characterization, and Fluorescent Properties
A zinc coordination polymer with the formula [Zn(pa)(L 1 )(H 2 O) 2 ] n ( I ) (L 1 = bis(4-(1 H -imidazol-1-yl) phenyl)methanone, H 2 pa = phthalic acid) is synthesized and structurally characterized. The single crystal X-ray diffraction analysis shows that Zn1 has a distorted octahedral geometry wi...
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| Published in: | Journal of structural chemistry 2019, Vol.60 (1), p.131-135 |
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| Main Authors: | , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c316t-868081322f0f20d502ff03c4da09bba34ce7c009fb0d69b34a35cc4c6d3013523 |
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| cites | cdi_FETCH-LOGICAL-c316t-868081322f0f20d502ff03c4da09bba34ce7c009fb0d69b34a35cc4c6d3013523 |
| container_end_page | 135 |
| container_issue | 1 |
| container_start_page | 131 |
| container_title | Journal of structural chemistry |
| container_volume | 60 |
| creator | Wang, G.-F. Sun, S.-W. |
| description | A zinc coordination polymer with the formula [Zn(pa)(L
1
)(H
2
O)
2
]
n
(
I
) (L
1
= bis(4-(1
H
-imidazol-1-yl) phenyl)methanone, H
2
pa = phthalic acid) is synthesized and structurally characterized. The single crystal X-ray diffraction analysis shows that Zn1 has a distorted octahedral geometry with two O atoms from two pa
2−
ligands and two N atoms from two L
1
ligands. Each L
1
acts as a bridging ligand to link the neighboring zinc ions to form a looped chain. The thermal stability and fluorescent properties of the complex are investigated. |
| doi_str_mv | 10.1134/S0022476619010189 |
| format | article |
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1
)(H
2
O)
2
]
n
(
I
) (L
1
= bis(4-(1
H
-imidazol-1-yl) phenyl)methanone, H
2
pa = phthalic acid) is synthesized and structurally characterized. The single crystal X-ray diffraction analysis shows that Zn1 has a distorted octahedral geometry with two O atoms from two pa
2−
ligands and two N atoms from two L
1
ligands. Each L
1
acts as a bridging ligand to link the neighboring zinc ions to form a looped chain. The thermal stability and fluorescent properties of the complex are investigated.</description><identifier>ISSN: 0022-4766</identifier><identifier>EISSN: 1573-8779</identifier><identifier>DOI: 10.1134/S0022476619010189</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Atomic ; Atomic/Molecular Structure and Spectra ; Chemistry ; Chemistry and Materials Science ; Coordination polymers ; Crystal structure ; Crystals ; Fluorescence ; Inorganic Chemistry ; Ligands ; Molecular ; Optical and Plasma Physics ; Physical Chemistry ; Polymers ; Single crystals ; Solid State Physics ; Structural analysis ; Thermal stability ; X-ray diffraction ; Zinc coordination</subject><ispartof>Journal of structural chemistry, 2019, Vol.60 (1), p.131-135</ispartof><rights>Pleiades Publishing, Ltd. 2019</rights><rights>Copyright Springer Nature B.V. 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-868081322f0f20d502ff03c4da09bba34ce7c009fb0d69b34a35cc4c6d3013523</citedby><cites>FETCH-LOGICAL-c316t-868081322f0f20d502ff03c4da09bba34ce7c009fb0d69b34a35cc4c6d3013523</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Wang, G.-F.</creatorcontrib><creatorcontrib>Sun, S.-W.</creatorcontrib><title>A Zinc Coordination Polymer Assembled from bis(4-(1H-Imidazol-1-yl)Phenyl)Methanone and Phthalic Acid: Synthesis, Structural Characterization, and Fluorescent Properties</title><title>Journal of structural chemistry</title><addtitle>J Struct Chem</addtitle><description>A zinc coordination polymer with the formula [Zn(pa)(L
1
)(H
2
O)
2
]
n
(
I
) (L
1
= bis(4-(1
H
-imidazol-1-yl) phenyl)methanone, H
2
pa = phthalic acid) is synthesized and structurally characterized. The single crystal X-ray diffraction analysis shows that Zn1 has a distorted octahedral geometry with two O atoms from two pa
2−
ligands and two N atoms from two L
1
ligands. Each L
1
acts as a bridging ligand to link the neighboring zinc ions to form a looped chain. The thermal stability and fluorescent properties of the complex are investigated.</description><subject>Atomic</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coordination polymers</subject><subject>Crystal structure</subject><subject>Crystals</subject><subject>Fluorescence</subject><subject>Inorganic Chemistry</subject><subject>Ligands</subject><subject>Molecular</subject><subject>Optical and Plasma Physics</subject><subject>Physical Chemistry</subject><subject>Polymers</subject><subject>Single crystals</subject><subject>Solid State Physics</subject><subject>Structural analysis</subject><subject>Thermal stability</subject><subject>X-ray diffraction</subject><subject>Zinc coordination</subject><issn>0022-4766</issn><issn>1573-8779</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNp1Uctq3DAUFSWFTtJ-QHeCbhKI0ivJY1vdDUPTBBI6MO2mGyNL17WCLU0leTH5o_5lPZlAFyGrw-W8uBxCPnK44lwWn7cAQhRVWXIFHHit3pAFX1aS1VWlTsjiQLMD_46cpvQAAKpW5YL8XdFfzhu6DiFa53V2wdNNGPYjRrpKCcd2QEu7GEbaunResHN-w25HZ_VjGBhn--Fi06Of4R5zr33wSLW3dNPP1-AMXRlnv9Dt3ucek0uXdJvjZPIU9UDXvY7aZIzu8an58sl6PUwhYjLoM93EsMOYHab35G2nh4QfnvGM_Lz--mN9w-6-f7tdr-6YkbzMrC5rqLkUooNOgF2C6DqQprAaVNtqWRiszPx914ItVSsLLZfGFKa0ErhcCnlGPh1zdzH8mTDl5iFM0c-VjRBccqWqCmYVP6pMDClF7JpddKOO-4ZDc1ikebHI7BFHT5q1_jfG_8mvm_4BohWOZw</recordid><startdate>2019</startdate><enddate>2019</enddate><creator>Wang, G.-F.</creator><creator>Sun, S.-W.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2019</creationdate><title>A Zinc Coordination Polymer Assembled from bis(4-(1H-Imidazol-1-yl)Phenyl)Methanone and Phthalic Acid: Synthesis, Structural Characterization, and Fluorescent Properties</title><author>Wang, G.-F. ; Sun, S.-W.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-868081322f0f20d502ff03c4da09bba34ce7c009fb0d69b34a35cc4c6d3013523</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Atomic</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coordination polymers</topic><topic>Crystal structure</topic><topic>Crystals</topic><topic>Fluorescence</topic><topic>Inorganic Chemistry</topic><topic>Ligands</topic><topic>Molecular</topic><topic>Optical and Plasma Physics</topic><topic>Physical Chemistry</topic><topic>Polymers</topic><topic>Single crystals</topic><topic>Solid State Physics</topic><topic>Structural analysis</topic><topic>Thermal stability</topic><topic>X-ray diffraction</topic><topic>Zinc coordination</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, G.-F.</creatorcontrib><creatorcontrib>Sun, S.-W.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of structural chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, G.-F.</au><au>Sun, S.-W.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Zinc Coordination Polymer Assembled from bis(4-(1H-Imidazol-1-yl)Phenyl)Methanone and Phthalic Acid: Synthesis, Structural Characterization, and Fluorescent Properties</atitle><jtitle>Journal of structural chemistry</jtitle><stitle>J Struct Chem</stitle><date>2019</date><risdate>2019</risdate><volume>60</volume><issue>1</issue><spage>131</spage><epage>135</epage><pages>131-135</pages><issn>0022-4766</issn><eissn>1573-8779</eissn><abstract>A zinc coordination polymer with the formula [Zn(pa)(L
1
)(H
2
O)
2
]
n
(
I
) (L
1
= bis(4-(1
H
-imidazol-1-yl) phenyl)methanone, H
2
pa = phthalic acid) is synthesized and structurally characterized. The single crystal X-ray diffraction analysis shows that Zn1 has a distorted octahedral geometry with two O atoms from two pa
2−
ligands and two N atoms from two L
1
ligands. Each L
1
acts as a bridging ligand to link the neighboring zinc ions to form a looped chain. The thermal stability and fluorescent properties of the complex are investigated.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0022476619010189</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0022-4766 |
| ispartof | Journal of structural chemistry, 2019, Vol.60 (1), p.131-135 |
| issn | 0022-4766 1573-8779 |
| language | eng |
| recordid | cdi_proquest_journals_2213199770 |
| source | Springer Nature |
| subjects | Atomic Atomic/Molecular Structure and Spectra Chemistry Chemistry and Materials Science Coordination polymers Crystal structure Crystals Fluorescence Inorganic Chemistry Ligands Molecular Optical and Plasma Physics Physical Chemistry Polymers Single crystals Solid State Physics Structural analysis Thermal stability X-ray diffraction Zinc coordination |
| title | A Zinc Coordination Polymer Assembled from bis(4-(1H-Imidazol-1-yl)Phenyl)Methanone and Phthalic Acid: Synthesis, Structural Characterization, and Fluorescent Properties |
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