Carbon xerogels electrochemical oxidation and correlation with their physico-chemical properties

The electrochemical oxidation of carbon represents a relevant limitation for the application of carbon-based materials at the electrodes of several electrochemical devices, like fuel cells, metal-air batteries, water electrolyzers or supercapacitors. Understanding the key influencing parameters is t...

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Bibliographic Details
Published in:Carbon (New York) 2019-04, Vol.144, p.382-394
Main Authors: Alegre, Cinthia, Sebastián, David, Lázaro, María J.
Format: Article
Language:English
Subjects:
Amorphous carbon
Amorphous materials
Carbon
Carbon electro-oxidation
Carbon xerogels
Chemical properties
Degradation
Disorder
Electrochemical oxidation
Electrodes
Electrolytic cells
Fuel cells
Organic chemistry
Oxidation
Oxygen groups
Parameters
Photoelectrons
Raman spectra
Xerogels
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Summary:The electrochemical oxidation of carbon represents a relevant limitation for the application of carbon-based materials at the electrodes of several electrochemical devices, like fuel cells, metal-air batteries, water electrolyzers or supercapacitors. Understanding the key influencing parameters is thus of paramount importance to prevent and avoid the degradation of carbon materials. In the present investigation, carbon xerogels (CXGs) as a model of synthetic amorphous carbon, were studied on the basis of different surface chemistry and structure. Electro-oxidation experiments consisted of potential holding (1.2 V vs. RHE) on electrodes prepared with CXGs. The results indicate that the presence of oxygen groups (-C-O) and a higher ordering degree hinder the carbon oxidation reaction. A sub-structural parameter considering both the amount of oxygen-free carbon atoms (C-C + C*-C-O) from X-ray photoelectron spectroscopy, and the disordering degree from Raman spectra (in terms of ID/IG) is here proposed as a new factor to evaluate the tendency of an amorphous carbon material, like xerogels, to be electrochemically oxidized. [Display omitted]
ISSN:0008-6223
1873-3891
DOI:10.1016/j.carbon.2018.12.065