Ba0.95Ca0.05Ce0.9Y0.1O3 as an electrolyte for proton-conducting ceramic fuel cells

• Published in: Electrochimica acta 2019-05, Vol.304, p.70-79
• Main Authors: Dudek, M., Lis, B., Lach, R., Daugėla, S., Šalkus, T., Kežionis, A., Mosiałek, M., Socha, R.P., Morgiel, J., Gajek, M., Sitarz, M., Ziąbka, M.
• Format: Article
• Language: English
• Subjects: Barium; Barium calcium yttrium cerate; Broadband impedance spectroscopy; Carbon dioxide; Ceramic proton-conducting electrolyte; Ceramics; Comparative studies; Corrosion resistance; Electrical resistivity; Electrochemical analysis; Electrolytes; Electrolytic cells; Fuel cells; Organic chemistry; Solid oxide fuel cell; Stability; X-ray diffraction
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2019.02.112

Comparative studies of the physicochemical and electrochemical properties of BaCe0.9Y0.1O3 and Ba0.95Ca0.05Ce0.9Y0.1O3 sintered ceramics are described. The orthorhombic (Pnma) space group was determined for both investigated samples within the temperature range 25–800 °C, using the X-ray diffraction method. A decrease in the cell volume of Ba0.95Ca0.05Ce0.9Y0.1O3 compared to that of BaCe0.9Y0.1O3 was observed within the investigated temperature range. It was found that the partial substitution of calcium for barium, resulting in Ba0.95Ca0.05Ce0.9Y0.1O3, caused an increase in specific free volume and global instability index compared to the original composition BaCe0.9Y0.1O3. Improvement of the chemical resistance of Ba0.95Ca0.05Ce0.9Y0.1O3 in a CO2 gas atmosphere was observed. It was found that Ba0.95Ca0.05Ce0.9Y0.1O3 exhibited a slightly lower level of electrical conductivity than BaCe0.9Y0.1O3 in air as well as in ArH2 gas atmospheres. The greater chemical resistance of Ba0.95Ca0.05Ce0.9Y0.1O3 in a CO2 gas atmosphere enhances the suitability of the modified material as an electrolyte for fuel cells with proton-conducting ceramics. The electrochemical response of the interface (La0.60Sr0.40)0.95Co0.20Fe0.80O3−δ|Ba0.95Ca0.05Ce0.9Y0.1O3 was also investigated within the applied potential range from −0.05 to −0.5 V in SOFC mode as well as from 0.05 to 0.5 V in SOEC mode); it was found that the current reached a fairly stable value over time.