1,8-Bis[2-(diphenylphosphoryl)phenoxy-4-phenyldiazenyl)]-3,6-dioxaoctane (L): Synthesis and Complexing and Ion-Selective Properties. Crystal and Molecular Structures of L · 0.25H2O and [LiL]I3 · MePh

The synthesis, IR and electronic absorption spectra, and ion-selective properties of 1,8-bis[2-(diphenylphosphoryl)phenoxy-4-phenyldiazenyl]-3,6-dioxaoctane (L), a new phosphoryl podand, are described. The crystal structures of L · 0.25H 2 O and the synthesized complex [LiL]I 3 · MePh were character...

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Bibliographic Details
Published in:Russian journal of inorganic chemistry 2019-02, Vol.64 (2), p.216-224
Main Authors: Ivanova, I. S., Ilyukhin, A. B., Polyakova, I. N., Rogacheva, Yu. I., Pyatova, E. N., Tsebrikova, G. S., Baulin, V. E., Tsivadze, A. Yu
Format: Article
Language:English
Subjects:
Absorption spectra
Chemical synthesis
Chemistry
Chemistry and Materials Science
Coordination Compounds
Crystal structure
Crystals
Inorganic Chemistry
Ions
Lithium
X-ray diffraction
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Summary:The synthesis, IR and electronic absorption spectra, and ion-selective properties of 1,8-bis[2-(diphenylphosphoryl)phenoxy-4-phenyldiazenyl]-3,6-dioxaoctane (L), a new phosphoryl podand, are described. The crystal structures of L · 0.25H 2 O and the synthesized complex [LiL]I 3 · MePh were characterized by X-ray diffraction. The composition of the plasticized polymeric membrane of a lithium-selective electrode based on L was determined.
ISSN:0036-0236
1531-8613
DOI:10.1134/S0036023619020098