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Catalytic Conjunctive Coupling of Carboxylic Acid Derivatives with 9‐BBN‐Derived Ate Complexes
β‐Boryl carbonyl compounds are produced by a Ni‐catalyzed cross‐coupling of vinylboron “ate” complexes and acid chloride or acid anhydride electrophiles. The reactions are efficient, being complete in as little as two minutes, and can be applied to a broad range of substrates. Kuppeln im Konjunktiv:...
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Published in: | Angewandte Chemie 2019-05, Vol.131 (20), p.6726-6730 |
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creator | Law, Chunyin Meng, Yan Koo, Seung Moh Morken, James P. |
description | β‐Boryl carbonyl compounds are produced by a Ni‐catalyzed cross‐coupling of vinylboron “ate” complexes and acid chloride or acid anhydride electrophiles. The reactions are efficient, being complete in as little as two minutes, and can be applied to a broad range of substrates.
Kuppeln im Konjunktiv: Eine neue Route zu nützlichen β‐Borylcarbonylverbindungen fußt auf der Ni‐katalysierten Addition von Alkenylboron‐„At”‐Komplexen an aktivierte Carbonsäuren. Die Reaktionen sind effizient – sie laufen innerhalb von nur zwei Minuten vollständig ab – und lassen sich auf vielfältige Substrate anwenden. |
doi_str_mv | 10.1002/ange.201901927 |
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Kuppeln im Konjunktiv: Eine neue Route zu nützlichen β‐Borylcarbonylverbindungen fußt auf der Ni‐katalysierten Addition von Alkenylboron‐„At”‐Komplexen an aktivierte Carbonsäuren. Die Reaktionen sind effizient – sie laufen innerhalb von nur zwei Minuten vollständig ab – und lassen sich auf vielfältige Substrate anwenden.</description><identifier>ISSN: 0044-8249</identifier><identifier>EISSN: 1521-3757</identifier><identifier>DOI: 10.1002/ange.201901927</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Acidic oxides ; Anhydrides ; Bor ; Carbonyl compounds ; Carbonyls ; Carboxylic acids ; Catalysis ; Chemistry ; Coupling (molecular) ; Katalyse ; Konjunktive Kupplungen ; Kreuzkupplungen ; Nickel ; Substrates</subject><ispartof>Angewandte Chemie, 2019-05, Vol.131 (20), p.6726-6730</ispartof><rights>2019 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1627-a70dfe0633227f10c23aa934ad99cb80f37be99e9276897e61369a5399c7ccd23</citedby><cites>FETCH-LOGICAL-c1627-a70dfe0633227f10c23aa934ad99cb80f37be99e9276897e61369a5399c7ccd23</cites><orcidid>0000-0002-9123-9791</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids></links><search><creatorcontrib>Law, Chunyin</creatorcontrib><creatorcontrib>Meng, Yan</creatorcontrib><creatorcontrib>Koo, Seung Moh</creatorcontrib><creatorcontrib>Morken, James P.</creatorcontrib><title>Catalytic Conjunctive Coupling of Carboxylic Acid Derivatives with 9‐BBN‐Derived Ate Complexes</title><title>Angewandte Chemie</title><description>β‐Boryl carbonyl compounds are produced by a Ni‐catalyzed cross‐coupling of vinylboron “ate” complexes and acid chloride or acid anhydride electrophiles. The reactions are efficient, being complete in as little as two minutes, and can be applied to a broad range of substrates.
Kuppeln im Konjunktiv: Eine neue Route zu nützlichen β‐Borylcarbonylverbindungen fußt auf der Ni‐katalysierten Addition von Alkenylboron‐„At”‐Komplexen an aktivierte Carbonsäuren. Die Reaktionen sind effizient – sie laufen innerhalb von nur zwei Minuten vollständig ab – und lassen sich auf vielfältige Substrate anwenden.</description><subject>Acidic oxides</subject><subject>Anhydrides</subject><subject>Bor</subject><subject>Carbonyl compounds</subject><subject>Carbonyls</subject><subject>Carboxylic acids</subject><subject>Catalysis</subject><subject>Chemistry</subject><subject>Coupling (molecular)</subject><subject>Katalyse</subject><subject>Konjunktive Kupplungen</subject><subject>Kreuzkupplungen</subject><subject>Nickel</subject><subject>Substrates</subject><issn>0044-8249</issn><issn>1521-3757</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNqFkL1OwzAUhS0EEqWwMltiTvFPGsdjGkpBqsoCs-U4TnGVJsFO2mbjEXhGngSHIhiRrnwt3e-cax8ArjGaYITIrazWekIQ5r4IOwEjPCU4oGzKTsEIoTAMYhLyc3Dh3AYhFBHGRyBLZSvLvjUKpnW16SrVmp32964pTbWGdQFTabP60JceSZTJ4Z22ZicHzMG9aV8h_3z_mM1W_vwe6Rwm7WCxbUp90O4SnBWydPrqp4_By_38OX0Ilk-LxzRZBgr7twSSobzQKKKUEFZgpAiVktNQ5pyrLEYFZZnmXPu_RTFnOsI04nJK_ZQplRM6BjdH38bWb512rdjUna38SkGIz4XGKOSemhwpZWvnrC5EY81W2l5gJIYcxZCj-M3RC_hRsDel7v-hRbJazP-0X0qweGY</recordid><startdate>20190513</startdate><enddate>20190513</enddate><creator>Law, Chunyin</creator><creator>Meng, Yan</creator><creator>Koo, Seung Moh</creator><creator>Morken, James P.</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-9123-9791</orcidid></search><sort><creationdate>20190513</creationdate><title>Catalytic Conjunctive Coupling of Carboxylic Acid Derivatives with 9‐BBN‐Derived Ate Complexes</title><author>Law, Chunyin ; Meng, Yan ; Koo, Seung Moh ; Morken, James P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1627-a70dfe0633227f10c23aa934ad99cb80f37be99e9276897e61369a5399c7ccd23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Acidic oxides</topic><topic>Anhydrides</topic><topic>Bor</topic><topic>Carbonyl compounds</topic><topic>Carbonyls</topic><topic>Carboxylic acids</topic><topic>Catalysis</topic><topic>Chemistry</topic><topic>Coupling (molecular)</topic><topic>Katalyse</topic><topic>Konjunktive Kupplungen</topic><topic>Kreuzkupplungen</topic><topic>Nickel</topic><topic>Substrates</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Law, Chunyin</creatorcontrib><creatorcontrib>Meng, Yan</creatorcontrib><creatorcontrib>Koo, Seung Moh</creatorcontrib><creatorcontrib>Morken, James P.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Angewandte Chemie</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Law, Chunyin</au><au>Meng, Yan</au><au>Koo, Seung Moh</au><au>Morken, James P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Catalytic Conjunctive Coupling of Carboxylic Acid Derivatives with 9‐BBN‐Derived Ate Complexes</atitle><jtitle>Angewandte Chemie</jtitle><date>2019-05-13</date><risdate>2019</risdate><volume>131</volume><issue>20</issue><spage>6726</spage><epage>6730</epage><pages>6726-6730</pages><issn>0044-8249</issn><eissn>1521-3757</eissn><abstract>β‐Boryl carbonyl compounds are produced by a Ni‐catalyzed cross‐coupling of vinylboron “ate” complexes and acid chloride or acid anhydride electrophiles. The reactions are efficient, being complete in as little as two minutes, and can be applied to a broad range of substrates.
Kuppeln im Konjunktiv: Eine neue Route zu nützlichen β‐Borylcarbonylverbindungen fußt auf der Ni‐katalysierten Addition von Alkenylboron‐„At”‐Komplexen an aktivierte Carbonsäuren. Die Reaktionen sind effizient – sie laufen innerhalb von nur zwei Minuten vollständig ab – und lassen sich auf vielfältige Substrate anwenden.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/ange.201901927</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0002-9123-9791</orcidid></addata></record> |
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subjects | Acidic oxides Anhydrides Bor Carbonyl compounds Carbonyls Carboxylic acids Catalysis Chemistry Coupling (molecular) Katalyse Konjunktive Kupplungen Kreuzkupplungen Nickel Substrates |
title | Catalytic Conjunctive Coupling of Carboxylic Acid Derivatives with 9‐BBN‐Derived Ate Complexes |
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