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Catalytic Conjunctive Coupling of Carboxylic Acid Derivatives with 9‐BBN‐Derived Ate Complexes

β‐Boryl carbonyl compounds are produced by a Ni‐catalyzed cross‐coupling of vinylboron “ate” complexes and acid chloride or acid anhydride electrophiles. The reactions are efficient, being complete in as little as two minutes, and can be applied to a broad range of substrates. Kuppeln im Konjunktiv:...

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Published in:Angewandte Chemie 2019-05, Vol.131 (20), p.6726-6730
Main Authors: Law, Chunyin, Meng, Yan, Koo, Seung Moh, Morken, James P.
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description β‐Boryl carbonyl compounds are produced by a Ni‐catalyzed cross‐coupling of vinylboron “ate” complexes and acid chloride or acid anhydride electrophiles. The reactions are efficient, being complete in as little as two minutes, and can be applied to a broad range of substrates. Kuppeln im Konjunktiv: Eine neue Route zu nützlichen β‐Borylcarbonylverbindungen fußt auf der Ni‐katalysierten Addition von Alkenylboron‐„At”‐Komplexen an aktivierte Carbonsäuren. Die Reaktionen sind effizient – sie laufen innerhalb von nur zwei Minuten vollständig ab – und lassen sich auf vielfältige Substrate anwenden.
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source Wiley-Blackwell Read & Publish Collection
subjects Acidic oxides
Anhydrides
Bor
Carbonyl compounds
Carbonyls
Carboxylic acids
Catalysis
Chemistry
Coupling (molecular)
Katalyse
Konjunktive Kupplungen
Kreuzkupplungen
Nickel
Substrates
title Catalytic Conjunctive Coupling of Carboxylic Acid Derivatives with 9‐BBN‐Derived Ate Complexes
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