Ionic mobility in Li x K1 − x Sn2F5 (x = 0–0.15) solid solutions obtained by mechanochemical synthesis

The solid solutions LixK1 − xSn2F5 (x = 0–0.15) were synthesized by the mechanochemical method. According to XRD and 19F MAS NMR data, the samples are isostructural to KSn2F5, which has superionic properties. The fluoride-ion jump frequency at a given temperature depends on the LiF concentration and...

Full description

Saved in:
Bibliographic Details
Published in:Ionics 2019-01, Vol.25 (4), p.1481-1486
Main Authors: Slobodyuk, A B, Usoltseva, T I, Polyantsev, M M, Kavun, V Y
Format: Article
Language:English
Subjects:
Fluorine
Ionic mobility
Lithium
Lithium fluoride
Lithium ions
NMR spectroscopy
Occupancy
Solid solutions
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page 1486
container_issue 4
container_start_page 1481
container_title Ionics
container_volume 25
creator Slobodyuk, A B
Usoltseva, T I
Polyantsev, M M
Kavun, V Y
description The solid solutions LixK1 − xSn2F5 (x = 0–0.15) were synthesized by the mechanochemical method. According to XRD and 19F MAS NMR data, the samples are isostructural to KSn2F5, which has superionic properties. The fluoride-ion jump frequency at a given temperature depends on the LiF concentration and is highest for x = 0.02. The amount of the mobile lithium ions at 420 K is maximal for Li0.075K0.925Sn2F5. Two types of fluorine positions with different jump frequencies are present in the structure of the compounds. Occupancy factors of the positions depend on the dopant concentration.
doi_str_mv 10.1007/s11581-018-2645-9
format article
fullrecord <record><control><sourceid>proquest</sourceid><recordid>TN_cdi_proquest_journals_2223206888</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2223206888</sourcerecordid><originalsourceid>FETCH-proquest_journals_22232068883</originalsourceid><addsrcrecordid>eNqNjT1OxDAUhC0EEuHnAHRPooHC8OxNbG9BhViBoIN-lWSN4lViQ54jJd2W0MINcxKMxAEo5huNZqRh7EzglUDU1yREYQRHYbhUecGXeywTRkmOWuE-y3CZa64x14fsiGiLqJSQOmP9Q_Cuhi5UrnVxAufhycEIj2Lefc4fX4kjPHu5KuBiTOEmCefdd7otLoFC6za_HKILniBUsXTebqCaoLN1U_pQN7ZzddkCTT42lhydsIPXsiV7-ufH7Hx193J7z9_68D5YiuttGHqfqrWUciFRGWMW_1v9ALSbVO4</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2223206888</pqid></control><display><type>article</type><title>Ionic mobility in Li x K1 − x Sn2F5 (x = 0–0.15) solid solutions obtained by mechanochemical synthesis</title><source>Springer Link</source><creator>Slobodyuk, A B ; Usoltseva, T I ; Polyantsev, M M ; Kavun, V Y</creator><creatorcontrib>Slobodyuk, A B ; Usoltseva, T I ; Polyantsev, M M ; Kavun, V Y</creatorcontrib><description>The solid solutions LixK1 − xSn2F5 (x = 0–0.15) were synthesized by the mechanochemical method. According to XRD and 19F MAS NMR data, the samples are isostructural to KSn2F5, which has superionic properties. The fluoride-ion jump frequency at a given temperature depends on the LiF concentration and is highest for x = 0.02. The amount of the mobile lithium ions at 420 K is maximal for Li0.075K0.925Sn2F5. Two types of fluorine positions with different jump frequencies are present in the structure of the compounds. Occupancy factors of the positions depend on the dopant concentration.</description><identifier>ISSN: 0947-7047</identifier><identifier>EISSN: 1862-0760</identifier><identifier>DOI: 10.1007/s11581-018-2645-9</identifier><language>eng</language><publisher>Heidelberg: Springer Nature B.V</publisher><subject>Fluorine ; Ionic mobility ; Lithium ; Lithium fluoride ; Lithium ions ; NMR spectroscopy ; Occupancy ; Solid solutions</subject><ispartof>Ionics, 2019-01, Vol.25 (4), p.1481-1486</ispartof><rights>Copyright Springer Nature B.V. 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Slobodyuk, A B</creatorcontrib><creatorcontrib>Usoltseva, T I</creatorcontrib><creatorcontrib>Polyantsev, M M</creatorcontrib><creatorcontrib>Kavun, V Y</creatorcontrib><title>Ionic mobility in Li x K1 − x Sn2F5 (x = 0–0.15) solid solutions obtained by mechanochemical synthesis</title><title>Ionics</title><description>The solid solutions LixK1 − xSn2F5 (x = 0–0.15) were synthesized by the mechanochemical method. According to XRD and 19F MAS NMR data, the samples are isostructural to KSn2F5, which has superionic properties. The fluoride-ion jump frequency at a given temperature depends on the LiF concentration and is highest for x = 0.02. The amount of the mobile lithium ions at 420 K is maximal for Li0.075K0.925Sn2F5. Two types of fluorine positions with different jump frequencies are present in the structure of the compounds. Occupancy factors of the positions depend on the dopant concentration.</description><subject>Fluorine</subject><subject>Ionic mobility</subject><subject>Lithium</subject><subject>Lithium fluoride</subject><subject>Lithium ions</subject><subject>NMR spectroscopy</subject><subject>Occupancy</subject><subject>Solid solutions</subject><issn>0947-7047</issn><issn>1862-0760</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqNjT1OxDAUhC0EEuHnAHRPooHC8OxNbG9BhViBoIN-lWSN4lViQ54jJd2W0MINcxKMxAEo5huNZqRh7EzglUDU1yREYQRHYbhUecGXeywTRkmOWuE-y3CZa64x14fsiGiLqJSQOmP9Q_Cuhi5UrnVxAufhycEIj2Lefc4fX4kjPHu5KuBiTOEmCefdd7otLoFC6za_HKILniBUsXTebqCaoLN1U_pQN7ZzddkCTT42lhydsIPXsiV7-ufH7Hx193J7z9_68D5YiuttGHqfqrWUciFRGWMW_1v9ALSbVO4</recordid><startdate>20190101</startdate><enddate>20190101</enddate><creator>Slobodyuk, A B</creator><creator>Usoltseva, T I</creator><creator>Polyantsev, M M</creator><creator>Kavun, V Y</creator><general>Springer Nature B.V</general><scope/></search><sort><creationdate>20190101</creationdate><title>Ionic mobility in Li x K1 − x Sn2F5 (x = 0–0.15) solid solutions obtained by mechanochemical synthesis</title><author>Slobodyuk, A B ; Usoltseva, T I ; Polyantsev, M M ; Kavun, V Y</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-proquest_journals_22232068883</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Fluorine</topic><topic>Ionic mobility</topic><topic>Lithium</topic><topic>Lithium fluoride</topic><topic>Lithium ions</topic><topic>NMR spectroscopy</topic><topic>Occupancy</topic><topic>Solid solutions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Slobodyuk, A B</creatorcontrib><creatorcontrib>Usoltseva, T I</creatorcontrib><creatorcontrib>Polyantsev, M M</creatorcontrib><creatorcontrib>Kavun, V Y</creatorcontrib><jtitle>Ionics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Slobodyuk, A B</au><au>Usoltseva, T I</au><au>Polyantsev, M M</au><au>Kavun, V Y</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ionic mobility in Li x K1 − x Sn2F5 (x = 0–0.15) solid solutions obtained by mechanochemical synthesis</atitle><jtitle>Ionics</jtitle><date>2019-01-01</date><risdate>2019</risdate><volume>25</volume><issue>4</issue><spage>1481</spage><epage>1486</epage><pages>1481-1486</pages><issn>0947-7047</issn><eissn>1862-0760</eissn><abstract>The solid solutions LixK1 − xSn2F5 (x = 0–0.15) were synthesized by the mechanochemical method. According to XRD and 19F MAS NMR data, the samples are isostructural to KSn2F5, which has superionic properties. The fluoride-ion jump frequency at a given temperature depends on the LiF concentration and is highest for x = 0.02. The amount of the mobile lithium ions at 420 K is maximal for Li0.075K0.925Sn2F5. Two types of fluorine positions with different jump frequencies are present in the structure of the compounds. Occupancy factors of the positions depend on the dopant concentration.</abstract><cop>Heidelberg</cop><pub>Springer Nature B.V</pub><doi>10.1007/s11581-018-2645-9</doi></addata></record>
fulltext fulltext
identifier ISSN: 0947-7047
ispartof Ionics, 2019-01, Vol.25 (4), p.1481-1486
issn 0947-7047
1862-0760
language eng
recordid cdi_proquest_journals_2223206888
source Springer Link
subjects Fluorine
Ionic mobility
Lithium
Lithium fluoride
Lithium ions
NMR spectroscopy
Occupancy
Solid solutions
title Ionic mobility in Li x K1 − x Sn2F5 (x = 0–0.15) solid solutions obtained by mechanochemical synthesis
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-29T02%3A03%3A46IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Ionic%20mobility%20in%20Li%20x%20K1%E2%80%89%E2%88%92%E2%80%89x%20Sn2F5%20(x%E2%80%89=%E2%80%890%E2%80%930.15)%20solid%20solutions%20obtained%20by%20mechanochemical%20synthesis&rft.jtitle=Ionics&rft.au=Slobodyuk,%20A%20B&rft.date=2019-01-01&rft.volume=25&rft.issue=4&rft.spage=1481&rft.epage=1486&rft.pages=1481-1486&rft.issn=0947-7047&rft.eissn=1862-0760&rft_id=info:doi/10.1007/s11581-018-2645-9&rft_dat=%3Cproquest%3E2223206888%3C/proquest%3E%3Cgrp_id%3Ecdi_FETCH-proquest_journals_22232068883%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2223206888&rft_id=info:pmid/&rfr_iscdi=true