Photogalvanic eff ect in porphyrin-pyrrolo[3′,4′:1,9]-(C60-Ih)[5,6]fullerene-2′,5′-dicarboxylate systems

The influence of molecular structural factors of covalently bound porphyrin-fullerene dyads and porphyrin—fullerene binary mixtures on photocurrent in model photoelectrochemical cells was studied. It was found that the photocurrent increased either by introducing solubilizing alkyl groups into the d...

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Bibliographic Details
Published in:Russian chemical bulletin 2019-04, Vol.68 (4), p.825-831
Main Authors: Androsov, D. V., Strelnikov, A. A., Konev, A. S., Lukyanov, D. A., Kazakova, A. V., Levin, O. V., Khlebnikov, A. F.
Format: Article
Language:English
Subjects:
Binary mixtures
Buckminsterfullerene
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
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Fullerenes
Inorganic Chemistry
Organic Chemistry
Photoelectric effect
Photoelectric emission
Photoelectrochemical devices
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Summary:The influence of molecular structural factors of covalently bound porphyrin-fullerene dyads and porphyrin—fullerene binary mixtures on photocurrent in model photoelectrochemical cells was studied. It was found that the photocurrent increased either by introducing solubilizing alkyl groups into the donor (porphyrin) or acceptor (fullerene) fragments, or by covalent binding porphyrin and fullerene into a donor-acceptor dyad.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-019-2491-6