Two Diastereomers of d-Limonene-Derived Cyclic Carbonates from d-Limonene Oxide and Carbon Dioxide with a Tetrabutylammonium Chloride Catalyst

Two diastereomers of d-limonene-derived five-membered cyclic carbonates were prepared from the corresponding isomers of d-limonene oxide with CO2. Their syntheses were catalyzed by commercially available tetrabutylammonium chloride with high stereoselectivity. The reaction behavior dependent on the...

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Bibliographic Details
Published in:Bulletin of the Chemical Society of Japan 2018-01, Vol.91 (1), p.92-94
Main Authors: Morikawa, Hiroshi, Minamoto, Masato, Gorou, Yuuta, Yamaguchi, Jun-ichi, Morinaga, Hisatoyo, Motokucho, Suguru
Format: Article
Language:English
Subjects:
Carbon dioxide
Carbonates
Isomers
Stereoselectivity
Tetrabutylammonium chloride
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Summary:Two diastereomers of d-limonene-derived five-membered cyclic carbonates were prepared from the corresponding isomers of d-limonene oxide with CO2. Their syntheses were catalyzed by commercially available tetrabutylammonium chloride with high stereoselectivity. The reaction behavior dependent on the reaction conditions such as CO2 pressure was clarified.
ISSN:0009-2673
1348-0634
DOI:10.1246/bcsj.20170300