Systematic Synthesis and Crystal Structures of Tetraaryltellurium Compounds Ar4TeIV

Hypervalent tetraaryltellurium(IV) compounds of the type Ar4TeIV (1: Ar = C6H5; 2: Ar = p-H3CC6H4; 3: Ar = p-t-BuC6H4; 4: Ar = p-F3CC6H4) were prepared via a convenient one-pot reaction between the isolated corresponding ArLi reagent and TeCl4. X-ray crystallographic analyses of 1–4 revealed distort...

Full description

Saved in:
Bibliographic Details
Published in:Bulletin of the Chemical Society of Japan 2019-03, Vol.92 (3), p.661-663
Main Authors: Kobayashi, Sho, Sugamata, Koh, Minoura, Mao
Format: Article
Language:English
Subjects:
Crystal structure
Crystallography
Crystals
Dihedral angle
Reagents
Citations: Items that this one cites
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Hypervalent tetraaryltellurium(IV) compounds of the type Ar4TeIV (1: Ar = C6H5; 2: Ar = p-H3CC6H4; 3: Ar = p-t-BuC6H4; 4: Ar = p-F3CC6H4) were prepared via a convenient one-pot reaction between the isolated corresponding ArLi reagent and TeCl4. X-ray crystallographic analyses of 1–4 revealed distorted pseudo-trigonal-bipyramidal (TBP) structures for Ar4Te and the TBP character was analyzed by the dihedral angle method.
ISSN:0009-2673
1348-0634
DOI:10.1246/bcsj.20180380