Protocol for nonisothermal cure analysis of thermoset composites

• Published in: Progress in organic coatings 2019-06, Vol.131, p.333-339
• Main Authors: Jouyandeh, Maryam, Paran, Seyed Mohammad Reza, Jannesari, Ali, Puglia, Debora, Saeb, Mohammad Reza
• Format: Article
• Language: English
• Subjects: Additives; Corrosion prevention; Crosslinking; Cure Index; Cure kinetics; Differential scanning calorimetry; Nanoparticles; Nonisothermal calorimetry; Organic chemistry; Pigments; Polymer matrix composites; Properties (attributes); Qualitative analysis; Quantitative analysis; Reaction kinetics; Reagents; Thermoset composite; Thermosetting resins
• ISSN: 0300-9440; 1873-331X
• DOI: 10.1016/j.porgcoat.2019.02.040

[Display omitted] •Proposed a comprehensive protocol for evaluating cure process in thermoset composites.•Defined and explained qualitative and quantitative cure analyses.•Specified a detailed route in terms of Cure Index, cure behavior and cure kinetics.•Provided all formulas and equations required for implementation of approach. Thermoset composites are elements of advanced devices, and their properties depend on their crosslinking state. Unsurprisingly, reports on the effect of addition of micro- and nanoparticles, pigments, additives, and reinforcing agents on the thermal, mechanical, thermomechanical, and anti-corrosion prioerties of thermoset systems include cure analysis-both qualitatively and quantitatively. The poor knowledge about cure state makes interpretations about ultimate properties of thermoset composites prone to criticism of crosslinking density consideration. There is a general agreement that a complete cure is the result of appropriate dispersion of particles in a highly-viscous system in which the state of filler-polymer interaction determines the efficiency of crosslinking. Typically, an external filler can facilitate or hinder curing reaction depending on the shape, size, content and surface chemistry of particles. This short communication proposes a protocol for either qualitative or quantitative analysis of cure in thermoset systems based on nonisothermal differential scanning calorimetry measurements. The proposed instruction allows taking a full image of crosslinking in terms of Cure Index, cure behavior, and cure kinetics in thermoset composites to understand/predict correlation between microstructure and properties.