Degradation of rhodamine B by a novel Fe3O4/SiO2 double-mesoporous-shelled hollow spheres through photo-Fenton process

• Published in: Materials chemistry and physics 2019-04, Vol.227, p.302-312
• Main Authors: Wu, Xingping, Nan, Zhaodong
• Format: Article
• Language: English
• Subjects: Catalysis; Catalytic activity; Degradation; Dissolution; Double-mesoporous-shell; Formation mechanism; Hydrogen peroxide; Iron oxides; Light irradiation; Magnetic hollow sphere; Photo-Fenton process; Rhodamine; Silica; Silicon dioxide
• ISSN: 0254-0584; 1879-3312
• DOI: 10.1016/j.matchemphys.2019.02.023

SiO2/Fe3O4 magnetic double-mesoporous-shelled hollow spheres (DMSHSs) were successfully prepared through a solvothermal method. The DMSHSs formation mechanism was proposed. At the beginning stage, soluble silicate ions were formed through the part of the silica spheres dissolution in the alkaline solution. Fe3+ ions tend to absorbed on the inner and outer surface of the hollow silica spheres, which induced the as-formed Fe3O4 anchored at the silica surface. Subsequently, the DMSHSs were generated through little by little dissolution of the silica. The as-prepared DMSHSs showed excellent catalytic activity in Fenton reaction for rhodamine B (RhB) degradation than the SiO2/Fe3O4 magnetic single-mesoporous-shelled hollow spheres (SMSHSs). About 97% of RhB was degraded under pH = 6.12, 0.2 g/L of DMSHSs, 1 mL of H2O2 and 20 mg/L of RhB with visible light irradiation for 180 min. The DMSHSs can be magnetically separated from the solution and possess good reusability. Simultaneously, the mechanism for the Fenton process was investigated. These results indicated that the as-formed DMSHSs may show great application prospects in Fenton field. [Display omitted] •SiO2/Fe3O4 magnetic double-mesoporous-shelled hollow spheres were synthesized.•The DMSHSs formation mechanism was proposed through the time-dependent experiments.•The DMSHSs displayed enhanced photo-Fenton catalytic activity than the SMSHSs.