NMR spectroscopy and ion pairing: Measuring and understanding how ions interact

Pulsed gradient spin-echo (PGSE) diffusion and Overhauser NMR data together with density functional theory (DFT) calculations afford a qualitative estimation of the amount of ion pairing, as well as insight into the structures of a variety of inorganic, organic, and organometallic salts.

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Bibliographic Details
Published in:Pure and applied chemistry 2009-01, Vol.81 (4), p.615-633
Main Author: Pregosin, Paul S.
Format: Article
Language:English
Subjects:
charge distribution
diffusion data
ion-pairing NOEs
NMR spectroscopy
Qualitative analysis
salt structure
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Description
Summary:Pulsed gradient spin-echo (PGSE) diffusion and Overhauser NMR data together with density functional theory (DFT) calculations afford a qualitative estimation of the amount of ion pairing, as well as insight into the structures of a variety of inorganic, organic, and organometallic salts.
ISSN:0033-4545
1365-3075
DOI:10.1351/PAC-CON-08-08-06