Modified mesoporous materials as Pd scavengers and catalyst supports

The use of mesoporous molecular sieves (MMSs) modified by mercaptopropyl trimethoxysilane (MPTMS) to scavenge Pd is described. The ordered mesoporous material displays excellent ability to remove Pd from organic and aqueous solutions. After only one treatment, a 500-ppm solution of PdCl in water can...

Full description

Saved in:
Bibliographic Details
Published in:Pure and applied chemistry 2007-02, Vol.79 (2), p.247-260
Main Authors: Crudden, Cathleen M., McEleney, Kevin, MacQuarrie, Stephanie L., Blanc, Alexandre, Sateesh, Mutyala, Webb, Jonathan D.
Format: Article
Language:English
Subjects:
Aqueous solutions
Catalysis
Catalysts
Chemical reactions
coupling reactions
heterogeneous
Leaching
micelle-templated materials
Molecular sieves
ordered materials
palladium
SBA-15
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c430t-a242a37eab814d28690e4290c2232358a4dacbc123dc4050df43f2e1d9edbde53
cites cdi_FETCH-LOGICAL-c430t-a242a37eab814d28690e4290c2232358a4dacbc123dc4050df43f2e1d9edbde53
container_end_page 260
container_issue 2
container_start_page 247
container_title Pure and applied chemistry
container_volume 79
creator Crudden, Cathleen M.
McEleney, Kevin
MacQuarrie, Stephanie L.
Blanc, Alexandre
Sateesh, Mutyala
Webb, Jonathan D.
description The use of mesoporous molecular sieves (MMSs) modified by mercaptopropyl trimethoxysilane (MPTMS) to scavenge Pd is described. The ordered mesoporous material displays excellent ability to remove Pd from organic and aqueous solutions. After only one treatment, a 500-ppm solution of PdCl in water can be reduced to 1 ppb. In addition, the resulting material is an effective, leach-proof catalyst for the Suzuki-Miyaura and Mizoroki-Heck reactions. Thus, the Suzuki-Miyaura reaction can be conducted in water at 80 °C with as little as 3 ppb Pd leaching. Hot filtrations and three-phase tests confirm that the catalyst acts without leaching Pd from the surface.
doi_str_mv 10.1351/pac200779020247
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2230125251</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2230125251</sourcerecordid><originalsourceid>FETCH-LOGICAL-c430t-a242a37eab814d28690e4290c2232358a4dacbc123dc4050df43f2e1d9edbde53</originalsourceid><addsrcrecordid>eNp1kEFLAzEQhYMoWKtnrwHPayeTpNs9eJBqVajoQc_LNJktW9rumuwq_femVBAETzMM73vDe0JcKrhW2qpRSw4B8rwABDT5kRgoPbaZhtweiwGA1pmxxp6KsxhXAGAKgwNx99z4uqrZyw3Hpm1C00e5oY5DTesoKcpXL6OjT94uOaTD1ktHHa13sZOxbxPRxXNxUiU1X_zMoXif3b9NH7P5y8PT9HaeOaOhywgNks6ZFhNlPE7GBbDBAhyiRm0nZDy5hVOovTNgwVdGV8jKF-wXnq0eiquDbxuaj55jV66aPmzTyzJZgEKLViXV6KByoYkxcFW2od5Q2JUKyn1V5Z-qEnFzIL5onZJ7XoZ-l5Zf-3_IvMA9_w1aX2-7</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2230125251</pqid></control><display><type>article</type><title>Modified mesoporous materials as Pd scavengers and catalyst supports</title><source>Free Full-Text Journals in Chemistry</source><creator>Crudden, Cathleen M. ; McEleney, Kevin ; MacQuarrie, Stephanie L. ; Blanc, Alexandre ; Sateesh, Mutyala ; Webb, Jonathan D.</creator><creatorcontrib>Crudden, Cathleen M. ; McEleney, Kevin ; MacQuarrie, Stephanie L. ; Blanc, Alexandre ; Sateesh, Mutyala ; Webb, Jonathan D.</creatorcontrib><description>The use of mesoporous molecular sieves (MMSs) modified by mercaptopropyl trimethoxysilane (MPTMS) to scavenge Pd is described. The ordered mesoporous material displays excellent ability to remove Pd from organic and aqueous solutions. After only one treatment, a 500-ppm solution of PdCl in water can be reduced to 1 ppb. In addition, the resulting material is an effective, leach-proof catalyst for the Suzuki-Miyaura and Mizoroki-Heck reactions. Thus, the Suzuki-Miyaura reaction can be conducted in water at 80 °C with as little as 3 ppb Pd leaching. Hot filtrations and three-phase tests confirm that the catalyst acts without leaching Pd from the surface.</description><identifier>ISSN: 0033-4545</identifier><identifier>EISSN: 1365-3075</identifier><identifier>DOI: 10.1351/pac200779020247</identifier><language>eng</language><publisher>Berlin: De Gruyter</publisher><subject>Aqueous solutions ; Catalysis ; Catalysts ; Chemical reactions ; coupling reactions ; heterogeneous ; Leaching ; micelle-templated materials ; Molecular sieves ; ordered materials ; palladium ; SBA-15</subject><ispartof>Pure and applied chemistry, 2007-02, Vol.79 (2), p.247-260</ispartof><rights>2013 Walter de Gruyter GmbH, Berlin/Boston</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c430t-a242a37eab814d28690e4290c2232358a4dacbc123dc4050df43f2e1d9edbde53</citedby><cites>FETCH-LOGICAL-c430t-a242a37eab814d28690e4290c2232358a4dacbc123dc4050df43f2e1d9edbde53</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Crudden, Cathleen M.</creatorcontrib><creatorcontrib>McEleney, Kevin</creatorcontrib><creatorcontrib>MacQuarrie, Stephanie L.</creatorcontrib><creatorcontrib>Blanc, Alexandre</creatorcontrib><creatorcontrib>Sateesh, Mutyala</creatorcontrib><creatorcontrib>Webb, Jonathan D.</creatorcontrib><title>Modified mesoporous materials as Pd scavengers and catalyst supports</title><title>Pure and applied chemistry</title><description>The use of mesoporous molecular sieves (MMSs) modified by mercaptopropyl trimethoxysilane (MPTMS) to scavenge Pd is described. The ordered mesoporous material displays excellent ability to remove Pd from organic and aqueous solutions. After only one treatment, a 500-ppm solution of PdCl in water can be reduced to 1 ppb. In addition, the resulting material is an effective, leach-proof catalyst for the Suzuki-Miyaura and Mizoroki-Heck reactions. Thus, the Suzuki-Miyaura reaction can be conducted in water at 80 °C with as little as 3 ppb Pd leaching. Hot filtrations and three-phase tests confirm that the catalyst acts without leaching Pd from the surface.</description><subject>Aqueous solutions</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemical reactions</subject><subject>coupling reactions</subject><subject>heterogeneous</subject><subject>Leaching</subject><subject>micelle-templated materials</subject><subject>Molecular sieves</subject><subject>ordered materials</subject><subject>palladium</subject><subject>SBA-15</subject><issn>0033-4545</issn><issn>1365-3075</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><recordid>eNp1kEFLAzEQhYMoWKtnrwHPayeTpNs9eJBqVajoQc_LNJktW9rumuwq_femVBAETzMM73vDe0JcKrhW2qpRSw4B8rwABDT5kRgoPbaZhtweiwGA1pmxxp6KsxhXAGAKgwNx99z4uqrZyw3Hpm1C00e5oY5DTesoKcpXL6OjT94uOaTD1ktHHa13sZOxbxPRxXNxUiU1X_zMoXif3b9NH7P5y8PT9HaeOaOhywgNks6ZFhNlPE7GBbDBAhyiRm0nZDy5hVOovTNgwVdGV8jKF-wXnq0eiquDbxuaj55jV66aPmzTyzJZgEKLViXV6KByoYkxcFW2od5Q2JUKyn1V5Z-qEnFzIL5onZJ7XoZ-l5Zf-3_IvMA9_w1aX2-7</recordid><startdate>20070201</startdate><enddate>20070201</enddate><creator>Crudden, Cathleen M.</creator><creator>McEleney, Kevin</creator><creator>MacQuarrie, Stephanie L.</creator><creator>Blanc, Alexandre</creator><creator>Sateesh, Mutyala</creator><creator>Webb, Jonathan D.</creator><general>De Gruyter</general><general>Walter de Gruyter GmbH</general><scope>AAYXX</scope><scope>CITATION</scope><scope>K9.</scope></search><sort><creationdate>20070201</creationdate><title>Modified mesoporous materials as Pd scavengers and catalyst supports</title><author>Crudden, Cathleen M. ; McEleney, Kevin ; MacQuarrie, Stephanie L. ; Blanc, Alexandre ; Sateesh, Mutyala ; Webb, Jonathan D.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c430t-a242a37eab814d28690e4290c2232358a4dacbc123dc4050df43f2e1d9edbde53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Aqueous solutions</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemical reactions</topic><topic>coupling reactions</topic><topic>heterogeneous</topic><topic>Leaching</topic><topic>micelle-templated materials</topic><topic>Molecular sieves</topic><topic>ordered materials</topic><topic>palladium</topic><topic>SBA-15</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Crudden, Cathleen M.</creatorcontrib><creatorcontrib>McEleney, Kevin</creatorcontrib><creatorcontrib>MacQuarrie, Stephanie L.</creatorcontrib><creatorcontrib>Blanc, Alexandre</creatorcontrib><creatorcontrib>Sateesh, Mutyala</creatorcontrib><creatorcontrib>Webb, Jonathan D.</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Health &amp; Medical Complete (Alumni)</collection><jtitle>Pure and applied chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Crudden, Cathleen M.</au><au>McEleney, Kevin</au><au>MacQuarrie, Stephanie L.</au><au>Blanc, Alexandre</au><au>Sateesh, Mutyala</au><au>Webb, Jonathan D.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Modified mesoporous materials as Pd scavengers and catalyst supports</atitle><jtitle>Pure and applied chemistry</jtitle><date>2007-02-01</date><risdate>2007</risdate><volume>79</volume><issue>2</issue><spage>247</spage><epage>260</epage><pages>247-260</pages><issn>0033-4545</issn><eissn>1365-3075</eissn><abstract>The use of mesoporous molecular sieves (MMSs) modified by mercaptopropyl trimethoxysilane (MPTMS) to scavenge Pd is described. The ordered mesoporous material displays excellent ability to remove Pd from organic and aqueous solutions. After only one treatment, a 500-ppm solution of PdCl in water can be reduced to 1 ppb. In addition, the resulting material is an effective, leach-proof catalyst for the Suzuki-Miyaura and Mizoroki-Heck reactions. Thus, the Suzuki-Miyaura reaction can be conducted in water at 80 °C with as little as 3 ppb Pd leaching. Hot filtrations and three-phase tests confirm that the catalyst acts without leaching Pd from the surface.</abstract><cop>Berlin</cop><pub>De Gruyter</pub><doi>10.1351/pac200779020247</doi><tpages>14</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 0033-4545
ispartof Pure and applied chemistry, 2007-02, Vol.79 (2), p.247-260
issn 0033-4545
1365-3075
language eng
recordid cdi_proquest_journals_2230125251
source Free Full-Text Journals in Chemistry
subjects Aqueous solutions
Catalysis
Catalysts
Chemical reactions
coupling reactions
heterogeneous
Leaching
micelle-templated materials
Molecular sieves
ordered materials
palladium
SBA-15
title Modified mesoporous materials as Pd scavengers and catalyst supports
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-27T00%3A40%3A09IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Modified%20mesoporous%20materials%20as%20Pd%20scavengers%20and%20catalyst%20supports&rft.jtitle=Pure%20and%20applied%20chemistry&rft.au=Crudden,%20Cathleen%20M.&rft.date=2007-02-01&rft.volume=79&rft.issue=2&rft.spage=247&rft.epage=260&rft.pages=247-260&rft.issn=0033-4545&rft.eissn=1365-3075&rft_id=info:doi/10.1351/pac200779020247&rft_dat=%3Cproquest_cross%3E2230125251%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c430t-a242a37eab814d28690e4290c2232358a4dacbc123dc4050df43f2e1d9edbde53%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2230125251&rft_id=info:pmid/&rfr_iscdi=true