New schemes for the synthesis of glycolipid oligosaccharide chains

The driving force for the constant improvement and development of synthetic methodologies in carbohydrate chemistry is the importance of natural oligosaccharide chains in numerous biological phenomena such as cell growth, differentiation, adhesion, etc. Here, we report our syntheses of the spacer-ar...

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Bibliographic Details
Published in:Pure and applied chemistry 2004-09, Vol.76 (9), p.1705-1714
Main Authors: Nifantiev, N. E., Sherman, A. A., Yudina, O. N., Cheshev, P. E., Tsvetkov, Y. E., Khatuntseva, E. A., Kornilov, A. V., Shashkov, A. S.
Format: Article
Language:English
Subjects:
Carbohydrates
Chains
Oligosaccharides
Organic chemistry
Stereoselectivity
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Summary:The driving force for the constant improvement and development of synthetic methodologies in carbohydrate chemistry is the importance of natural oligosaccharide chains in numerous biological phenomena such as cell growth, differentiation, adhesion, etc. Here, we report our syntheses of the spacer-armed oligosaccharides of sialylated - and -, -, , and sulfoglucuronylparagloboside-series, which include new rationally designed synthetic blocks, efficient solutions for the stereoselective construction of glycosidic bonds, and novel protection group strategies.
ISSN:0033-4545
1365-3075
DOI:10.1351/pac200476091705