Rearrangements in the nona-and azanonaborane clusters

In the conversion of nonaboranes B SMe to azanonaboranes B NH -NHR, one boron atom is lost. This boron atom was identified, and a pathway for the rearrangement of the cluster is proposed, based on the fate of covalently labeled boron atoms.

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Bibliographic Details
Published in:Pure and applied chemistry 2003-09, Vol.75 (9), p.1207-1210
Main Authors: El-Zaria, M., Dörfler, U., Gabel, D.
Format: Article
Language:English
Subjects:
Boron
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Description
Summary:In the conversion of nonaboranes B SMe to azanonaboranes B NH -NHR, one boron atom is lost. This boron atom was identified, and a pathway for the rearrangement of the cluster is proposed, based on the fate of covalently labeled boron atoms.
ISSN:0033-4545
1365-3075
DOI:10.1351/pac200375091207