A Transition‐Metal‐Free One‐Pot Cascade Process for Transformation of Primary Alcohols (RCH2OH) to Nitriles (RCN) Mediated by SO2F2

A new transition‐metal‐free one‐pot cascade process for the direct conversion of alcohols to nitriles was developed without introducing an “additional carbon atom”. This protocol allows transformations of readily available, inexpensive, and abundant alcohols to highly valuable nitriles. A new transi...

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Bibliographic Details
Published in:European journal of organic chemistry 2019-06, Vol.2019 (20), p.3190-3194
Main Authors: Jiang, Ying, Sun, Bing, Fang, Wan‐Yin, Qin, Hua‐Li
Format: Article
Language:English
Subjects:
Alcohol
Alcohols
Direct conversion
Nitriles
One‐pot
Sulfuryl fluoride
Transformations
Transition‐metal free
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Summary:A new transition‐metal‐free one‐pot cascade process for the direct conversion of alcohols to nitriles was developed without introducing an “additional carbon atom”. This protocol allows transformations of readily available, inexpensive, and abundant alcohols to highly valuable nitriles. A new transition‐metal‐free one‐pot cascade process for the direct conversion of alcohols to nitriles was developed without introducing an “additional carbon atom”. This protocol allows transformations of readily available, inexpensive, and abundant alcohols to highly valuable nitriles.
ISSN:1434-193X
1099-0690
DOI:10.1002/ejoc.201900478