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Kinetic approach for the adsorption-photodecomposition properties of mesoporous silica-titania
We have fabricated mesoporous silica-titania by a sol–gel method and evaluated the photocatalytic activity using acetaldehyde. The synthesized mesoporous silica-titania was effective for the removal of acetaldehyde from gas phase by adsorption and photodecomposition. In this study, the kinetic appro...
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Published in: | Journal of the Ceramic Society of Japan 2019/04/01, Vol.127(4), pp.242-248 |
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container_end_page | 248 |
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container_start_page | 242 |
container_title | Journal of the Ceramic Society of Japan |
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creator | HIRATA, Shingo INADA, Miki ENOMOTO, Naoya HAYASHI, Katsuro HOJO, Junichi |
description | We have fabricated mesoporous silica-titania by a sol–gel method and evaluated the photocatalytic activity using acetaldehyde. The synthesized mesoporous silica-titania was effective for the removal of acetaldehyde from gas phase by adsorption and photodecomposition. In this study, the kinetic approach was carried out in order to clarify the adsorption-photodecomposition property of mesoporous silica-titania. The adsorption, direct photodecomposition and concerted adsorption-photodecomposition can be separately described in our simulation curves, which indicates that the adsorbability strongly affects the removal of acetaldehyde in the early stage and the photodecomposition after the strong adsorption of acetaldehyde on mesoporous silica-titania is important for the complete removal of acetaldehyde from gas phase. |
doi_str_mv | 10.2109/jcersj2.19003 |
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The synthesized mesoporous silica-titania was effective for the removal of acetaldehyde from gas phase by adsorption and photodecomposition. In this study, the kinetic approach was carried out in order to clarify the adsorption-photodecomposition property of mesoporous silica-titania. The adsorption, direct photodecomposition and concerted adsorption-photodecomposition can be separately described in our simulation curves, which indicates that the adsorbability strongly affects the removal of acetaldehyde in the early stage and the photodecomposition after the strong adsorption of acetaldehyde on mesoporous silica-titania is important for the complete removal of acetaldehyde from gas phase.</description><identifier>ISSN: 1882-0743</identifier><identifier>EISSN: 1348-6535</identifier><identifier>DOI: 10.2109/jcersj2.19003</identifier><language>eng</language><publisher>Tokyo: The Ceramic Society of Japan</publisher><subject>Acetaldehyde ; Adsorbent ; Adsorption ; Catalytic activity ; Decomposition reactions ; Kinetic analysis ; Mesoporous silica-titania ; Photocatalysis ; Photocatalyst ; Photodecomposition ; Silicon dioxide ; Sol-gel processes ; Tin ; Vapor phases</subject><ispartof>Journal of the Ceramic Society of Japan, 2019/04/01, Vol.127(4), pp.242-248</ispartof><rights>2019 The Ceramic Society of Japan</rights><rights>Copyright Japan Science and Technology Agency 2019</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c533t-286c011209098d99bd52c20c33bad1e4ac825437ed59c7131eb7647db669cc153</citedby><cites>FETCH-LOGICAL-c533t-286c011209098d99bd52c20c33bad1e4ac825437ed59c7131eb7647db669cc153</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,778,782,1878,27911,27912</link.rule.ids></links><search><creatorcontrib>HIRATA, Shingo</creatorcontrib><creatorcontrib>INADA, Miki</creatorcontrib><creatorcontrib>ENOMOTO, Naoya</creatorcontrib><creatorcontrib>HAYASHI, Katsuro</creatorcontrib><creatorcontrib>HOJO, Junichi</creatorcontrib><title>Kinetic approach for the adsorption-photodecomposition properties of mesoporous silica-titania</title><title>Journal of the Ceramic Society of Japan</title><addtitle>J. Ceram. Soc. Japan</addtitle><description>We have fabricated mesoporous silica-titania by a sol–gel method and evaluated the photocatalytic activity using acetaldehyde. The synthesized mesoporous silica-titania was effective for the removal of acetaldehyde from gas phase by adsorption and photodecomposition. In this study, the kinetic approach was carried out in order to clarify the adsorption-photodecomposition property of mesoporous silica-titania. The adsorption, direct photodecomposition and concerted adsorption-photodecomposition can be separately described in our simulation curves, which indicates that the adsorbability strongly affects the removal of acetaldehyde in the early stage and the photodecomposition after the strong adsorption of acetaldehyde on mesoporous silica-titania is important for the complete removal of acetaldehyde from gas phase.</description><subject>Acetaldehyde</subject><subject>Adsorbent</subject><subject>Adsorption</subject><subject>Catalytic activity</subject><subject>Decomposition reactions</subject><subject>Kinetic analysis</subject><subject>Mesoporous silica-titania</subject><subject>Photocatalysis</subject><subject>Photocatalyst</subject><subject>Photodecomposition</subject><subject>Silicon dioxide</subject><subject>Sol-gel processes</subject><subject>Tin</subject><subject>Vapor phases</subject><issn>1882-0743</issn><issn>1348-6535</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpFkDtPwzAQxy0EEqUwsltiTvErD4-oKg9RiQVWLOfiEEdtbGx34Nvjtqgsd6e7373-CN1SsmCUyPsRTIgjW1BJCD9DM8pFU1QlL89z3DSsILXgl-gqxpGQignezNDnq51MsoC198FpGHDvAk6DwbqLLvhk3VT4wSXXGXBb76Ldp3CGvQnJmohdj7cmOu-C20Uc7caCLpJNerL6Gl30ehPNzZ-fo4_H1fvyuVi_Pb0sH9YFlJyngjUVEEoZkUQ2nZRtVzJgBDhvdUeN0NCwUvDadKWEmnJq2roSdddWlQSgJZ-ju-PcfNf3zsSkRrcLU16pGOOsyvIImaniSEFwMQbTKx_sVocfRYnaS6j-JFQHCTO_OvJjTPrLnGidH4eN-adZrcTBHvpOdRh0UGbiv-3yf7E</recordid><startdate>20190401</startdate><enddate>20190401</enddate><creator>HIRATA, Shingo</creator><creator>INADA, Miki</creator><creator>ENOMOTO, Naoya</creator><creator>HAYASHI, Katsuro</creator><creator>HOJO, Junichi</creator><general>The Ceramic Society of Japan</general><general>Japan Science and Technology Agency</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20190401</creationdate><title>Kinetic approach for the adsorption-photodecomposition properties of mesoporous silica-titania</title><author>HIRATA, Shingo ; INADA, Miki ; ENOMOTO, Naoya ; HAYASHI, Katsuro ; HOJO, Junichi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c533t-286c011209098d99bd52c20c33bad1e4ac825437ed59c7131eb7647db669cc153</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Acetaldehyde</topic><topic>Adsorbent</topic><topic>Adsorption</topic><topic>Catalytic activity</topic><topic>Decomposition reactions</topic><topic>Kinetic analysis</topic><topic>Mesoporous silica-titania</topic><topic>Photocatalysis</topic><topic>Photocatalyst</topic><topic>Photodecomposition</topic><topic>Silicon dioxide</topic><topic>Sol-gel processes</topic><topic>Tin</topic><topic>Vapor phases</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>HIRATA, Shingo</creatorcontrib><creatorcontrib>INADA, Miki</creatorcontrib><creatorcontrib>ENOMOTO, Naoya</creatorcontrib><creatorcontrib>HAYASHI, Katsuro</creatorcontrib><creatorcontrib>HOJO, Junichi</creatorcontrib><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of the Ceramic Society of Japan</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>HIRATA, Shingo</au><au>INADA, Miki</au><au>ENOMOTO, Naoya</au><au>HAYASHI, Katsuro</au><au>HOJO, Junichi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Kinetic approach for the adsorption-photodecomposition properties of mesoporous silica-titania</atitle><jtitle>Journal of the Ceramic Society of Japan</jtitle><addtitle>J. Ceram. Soc. Japan</addtitle><date>2019-04-01</date><risdate>2019</risdate><volume>127</volume><issue>4</issue><spage>242</spage><epage>248</epage><pages>242-248</pages><issn>1882-0743</issn><eissn>1348-6535</eissn><abstract>We have fabricated mesoporous silica-titania by a sol–gel method and evaluated the photocatalytic activity using acetaldehyde. The synthesized mesoporous silica-titania was effective for the removal of acetaldehyde from gas phase by adsorption and photodecomposition. In this study, the kinetic approach was carried out in order to clarify the adsorption-photodecomposition property of mesoporous silica-titania. The adsorption, direct photodecomposition and concerted adsorption-photodecomposition can be separately described in our simulation curves, which indicates that the adsorbability strongly affects the removal of acetaldehyde in the early stage and the photodecomposition after the strong adsorption of acetaldehyde on mesoporous silica-titania is important for the complete removal of acetaldehyde from gas phase.</abstract><cop>Tokyo</cop><pub>The Ceramic Society of Japan</pub><doi>10.2109/jcersj2.19003</doi><tpages>7</tpages><oa>free_for_read</oa></addata></record> |
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subjects | Acetaldehyde Adsorbent Adsorption Catalytic activity Decomposition reactions Kinetic analysis Mesoporous silica-titania Photocatalysis Photocatalyst Photodecomposition Silicon dioxide Sol-gel processes Tin Vapor phases |
title | Kinetic approach for the adsorption-photodecomposition properties of mesoporous silica-titania |
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