From on high: Geochemistry of alpine springs, Niwot Ridge, Colorado Front Range, USA

• Published in: Hydrological processes 2019-06, Vol.33 (12), p.1756-1774
• Main Authors: Fields, Jordan F., Dethier, David P.
• Format: Article
• Language: English
• Subjects: alpine springs; Basins; Calcite; Calcium; Calcium ions; Catchment area; Catchments; Cations; Chemical weathering; Chemistry; Coastal inlets; Downstream; Elevation; Geochemistry; Global temperatures; Groundwater; Groundwater chemistry; Hydrology; Kaolinite; mean transit time; Minerals; Montmorillonite; Montmorillonites; Mountains; Organic chemistry; orthoclase; Plagioclase; Precipitation; Rainfall; Regolith; Silicate minerals; Silicates; Silicon; Snowmelt; Solutes; Solutions; Spring; Trace minerals; Transit time; Water springs; Weathering
• ISSN: 0885-6087; 1099-1085
• DOI: 10.1002/hyp.13436

Snowmelt‐fed springs and small (0.5 km2) upland catchments in alpine areas of the western United States contribute significantly to the quantity and inorganic chemistry of water delivered to downstream basins but have not been studied extensively. Mineral weathering, transit time, and hydrologic mixing control the solute chemistry of waters that drain the upland zone of Niwot Ridge, Colorado Front Range, and adjacent areas in the granitic core of the Southern Rocky Mountains. Water in 37 springs sampled in this study flows in generally short steep paths (~0.3 km) through shallow regolith with mean transit times (MTT) of weeks to months, producing solutions dominated by Si, Ca2+, Na+, and HCO3−, locally SO42−. Rock type is a significant control on spring, surface, and shallow groundwater chemistry, and plagioclase (oligoclase) is the major source of dissolved Na+ and Si. Concentrations of Ca2+ exceed stoichiometric predictions of oligoclase weathering by ~3.5×; excess Ca2+ likely represents weathering of aeolian material, vein calcite, or trace minerals. Concentrations of base cations and Si increase slowly with estimated MTT of 0.2 years for Niwot Ridge spring waters, and several years for shallow groundwater sampled by wells. Chemical weathering of silicate minerals is slow with estimated rates of ~2.0 and 0.2 pmol·m−2·s−1 for oligoclase and microcline, respectively; the most mineralized spring waters are saturated only with respect to kaolinite and montmorillonite. More than 50% of the dissolved base cations + Si measured in Boulder Creek at Orodell (~25 km downstream) accumulate before water emerges from alpine springs on Niwot Ridge. Warming global temperatures are shifting more high‐elevation precipitation to rain, potentially changing run‐off patterns, transit time, and solute loads. Acquisition of solutes by alpine waters thus has implications far beyond small upland catchments.