Polymerization of Vinyl Monomers in the Presence of 4,6-Di-tert-butyl-N-(2,6-diisopropylphenyl)-o-iminobenzoquinone

— Features of radical polymerization of several vinyl monomers in the presence of 4,6-di- tert -butyl- N -(2,6-diisopropylphenyl)- o -iminobenzoquinone were studied. This compound was found to have an effect on the kinetic regularities of the synthesis of polymers at different temperatures and their...

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Bibliographic Details
Published in:Polymer science. Series B 2019-03, Vol.61 (2), p.132-147
Main Authors: Lizyakina, O. S., Vaganova, L. B., Chegerev, M. G., Piskunov, A. V., Grishin, D. F.
Format: Article
Language:English
Subjects:
Block copolymers
Chemical synthesis
Chemistry
Chemistry and Materials Science
Monomers
Polymer Sciences
Polymerization
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Summary:— Features of radical polymerization of several vinyl monomers in the presence of 4,6-di- tert -butyl- N -(2,6-diisopropylphenyl)- o -iminobenzoquinone were studied. This compound was found to have an effect on the kinetic regularities of the synthesis of polymers at different temperatures and their molecular weight characteristics. Optimum conditions for the preparation of corresponding polymers and block copolymers involving 4,6-di- tert -butyl- N -(2,6-diisopropylphenyl)- o -iminobenzoquinone in a wide range of molecular weights and compositions were determined.
ISSN:1560-0904
1555-6123
DOI:10.1134/S1560090419020064