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Hydrosilyl Group-directed Iridium-catalyzed peri-Selective C–H Borylation of Ring-fused (Hetero)Arenes
The iridium-catalyzed direct C–H borylation of ring-fused (hetero)arenes afforded borylated products in a peri-selective manner, directed by a proximal hydrosilyl group. Further selective transformations of the boryl and silyl groups enabled the synthesis of various multisubstituted (hetero)arenes,...
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Published in: | Chemistry letters 2018-10, Vol.47 (10), p.1251-1254 |
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Main Authors: | , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | The iridium-catalyzed direct C–H borylation of ring-fused (hetero)arenes afforded borylated products in a peri-selective manner, directed by a proximal hydrosilyl group. Further selective transformations of the boryl and silyl groups enabled the synthesis of various multisubstituted (hetero)arenes, such as 1,8-disubstituted naphthalenes and 3,4-diarylindole. |
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ISSN: | 0366-7022 1348-0715 |
DOI: | 10.1246/cl.180594 |