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Hydrosilyl Group-directed Iridium-catalyzed peri-Selective C–H Borylation of Ring-fused (Hetero)Arenes

The iridium-catalyzed direct C–H borylation of ring-fused (hetero)arenes afforded borylated products in a peri-selective manner, directed by a proximal hydrosilyl group. Further selective transformations of the boryl and silyl groups enabled the synthesis of various multisubstituted (hetero)arenes,...

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Bibliographic Details
Published in:Chemistry letters 2018-10, Vol.47 (10), p.1251-1254
Main Authors: Sumida, Yuto, Harada, Ryu, Sumida, Tomoe, Hashizume, Daisuke, Hosoya, Takamitsu
Format: Article
Language:English
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Summary:The iridium-catalyzed direct C–H borylation of ring-fused (hetero)arenes afforded borylated products in a peri-selective manner, directed by a proximal hydrosilyl group. Further selective transformations of the boryl and silyl groups enabled the synthesis of various multisubstituted (hetero)arenes, such as 1,8-disubstituted naphthalenes and 3,4-diarylindole.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.180594