Modular Synthesis of Unsymmetrical Doubly-ring-fused Benzene Derivatives Based on a Sequential Ring Construction Strategy Using Oxadiazinones as a Platform Molecule

An efficient benzene ring construction method using oxadiazinones as a platform molecule has been developed. Sequential reactions of oxadiazinones with cycloalkynes and arynes afforded partially reduced polyaromatics. This method enables facile preparation of various unsymmetrical doubly-ring-fused...

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Published in:Chemistry letters 2019-06, Vol.48 (6), p.582-585
Main Authors: Meguro, Tomohiro, Chen, Shengnan, Kanemoto, Kazuya, Yoshida, Suguru, Hosoya, Takamitsu
Format: Article
Language:English
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Benzene
Derivatives
Hydrocarbons
Price increases
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creator Meguro, Tomohiro
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description An efficient benzene ring construction method using oxadiazinones as a platform molecule has been developed. Sequential reactions of oxadiazinones with cycloalkynes and arynes afforded partially reduced polyaromatics. This method enables facile preparation of various unsymmetrical doubly-ring-fused benzene derivatives including multisubstituted tetrahydroanthracenes and anthracenes.
doi_str_mv 10.1246/cl.190118
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source Oxford Journals Online
subjects Benzene
Derivatives
Hydrocarbons
Price increases
title Modular Synthesis of Unsymmetrical Doubly-ring-fused Benzene Derivatives Based on a Sequential Ring Construction Strategy Using Oxadiazinones as a Platform Molecule
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